About Durability of Biodegradable Polymers: Structure/Degradability Relationships

被引:17
作者
Commereuc, S. [1 ,3 ]
Askanian, H. [2 ,3 ]
Verney, V. [2 ,3 ]
Celli, A. [4 ]
Marchese, P. [4 ]
机构
[1] Clermont Univ, ENSCCF, LPMM, BP 10448, F-63000 Clermont Ferrand, France
[2] Univ Blaise Pascal, Clermont Univ, LPMM, Clermont Ferrand F-63000, France
[3] CNRS, UMR 6505, LPMM, F-63174 Aubiere, France
[4] Dipartimento Chim, Appl Sci Mat, Bologna 40131, Italy
来源
MODERN TRENDS IN POLYMER SCIENCE-EPF 09 | 2010年 / 296卷
关键词
biodegradable; copolymerization; degradation; polyesters; rheology; RHEOLOGICAL PROPERTIES; RANDOM COPOLYMERS; THERMAL-BEHAVIOR; MELTS;
D O I
10.1002/masy.201051052
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Up to now materials were chosen to satisfy specific property(ies) in relation with the required application. Nowadays, a specific attention has to be devoted to the durability of this property regarding to the lifetime duration. It is the reason why, we paid attention about degradability. Thus, a screening of bio- and photodegradability of various selected (co)polyesters has been achieved in order to get better insights about structure / durability relationships. We developed tools allowing the prediction of the behavior of materials upon ageing and the evolution of their properties, regarding to their initial chemical structures. Hence, we could be able to design (co)polyesters characterized by well-adapted physical, thermal and mechanical properties, but also, with high photostability and/or high biodegradability.
引用
收藏
页码:378 / +
页数:3
相关论文
共 18 条
  • [1] [Anonymous], 1999, 14852 ISO
  • [2] Influence of molecular structure and stereochemistry of the 1,4-cyclohexylene ring on thermal and mechanical behavior of poly(butylene 1,4-cyclohexanedicarboxylate)
    Berti, Corrado
    Celli, Annamaria
    Marchese, Paola
    Marianucci, Elisabetta
    Barbiroli, Giancarlo
    Di Credico, Francesco
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (13) : 1333 - 1344
  • [3] Novel copolyesters based on poly(alkylene dicarboxylate)s: 2. Thermal behavior and biodegradation of fully aliphatic random copolymers containing 1,4-cyclohexylene rings
    Berti, Corrado
    Celli, Annamaria
    Marchese, Paola
    Barbiroli, Giancarlo
    Di Credico, Francesco
    Verney, Vincent
    Commereuc, Sophie
    [J]. EUROPEAN POLYMER JOURNAL, 2009, 45 (08) : 2402 - 2412
  • [4] Novel copolyesters based on poly(alkylene dicarboxylate)s: 1. Thermal behavior and biodegradation of aliphatic-aromatic random copolymers
    Berti, Corrado
    Celli, Annamaria
    Marchese, Paola
    Barbiroli, Giancarlo
    Di Credico, Francesco
    Verney, V.
    Commereuc, Sophie
    [J]. EUROPEAN POLYMER JOURNAL, 2008, 44 (11) : 3650 - 3661
  • [5] Thermal properties of poly(alkylene dicarboxylate)s derived from 1,12-dodecanedioic acid and even aliphatic diols
    Celli, Annamaria
    Barbiroli, Giancarlo
    Berti, Corrado
    Francesco, Di Credico
    Lorenzetti, Cesare
    Marchese, Paola
    Marianucci, Elisabetta
    [J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2007, 45 (09) : 1053 - 1067
  • [6] Photooxidation of polyoctenamer: viscoelastic assessment of gel formation
    Commereuc, S
    Bonhomme, S
    Verney, V
    Lacoste, J
    [J]. POLYMER, 2000, 41 (03) : 917 - 923
  • [7] Iwata T, 1999, MACROMOL CHEM PHYSIC, V200, P2429, DOI 10.1002/(SICI)1521-3935(19991101)200:11<2429::AID-MACP2429>3.0.CO
  • [8] 2-#
  • [9] Ageing of elastomers: a molecular approach based on rheological characterization
    Kumar, A
    Commereuc, S
    Verney, V
    [J]. POLYMER DEGRADATION AND STABILITY, 2004, 85 (02) : 751 - 757
  • [10] LEMAIRE J, 1986, KUNSTST-GER PLAST+, V76, P149