Synthesis and X-ray crystal structure of bis-3,3′-(nitro-NNO-azoxy)-difurazanyl ether

被引：0

作者：

Sheremetev, AB ^{[1
]}

Semenov, SE ^{[1
]}

Kuzmin, VS ^{[1
]}

Strelenko, YA ^{[1
]}

Ioffe, SL ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 1998年 / 4卷 / 06期

关键词：

azo compounds; furazans; heterocycles; nitro groups; structure elucidation;

D O I：

10.1002/(SICI)1521-3765(19980615)4:6<1023::AID-CHEM1023>3.3.CO;2-I

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two approaches to the synthesis of bis-3,3'-(nitro-NNO-azoxy)difurazanyl ether 2 have been tested, that is, varying the sequence of the introduction of the nitro-NNO-azoxy group and ether bridge. Difurazanyl ether formation through base-promoted transformation of nitrofurazans has been studied in which the nitro groups were activated by ortho electron-withdrawing substituents such as nitro-NNO-azoxy and tert-butyl-NNO-azoxy groups. The nitro-NNO-azoxy group was formed by destructive N-nitration of the tert-butyl-NNO-azoxy group. The X-ray crystal structure of 2 is reported.

引用

页码：1023 / 1026

页数：4

共 50 条

[21] Synthesis, Crystal Structure and Thermal Behavior of 3,3'-Bis(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl-ONN-azoxy)azoxyfurazan(BDDAF)
State Key Laboratory of Fluorine & Nitrogen Chemical, Xi'an
710065, China
不详
710065, China
Huozhayao Xuebao, 1600, 5 (45-50):
[22] Synthesis and X-ray crystal structure of (-)-calicheamicinone
Clive, DLJ
Bo, YX
Selvakumar, N
McDonald, R
Santarsiero, BD
TETRAHEDRON, 1999, 55 (11) : 3277 - 3290
[23] Synthesis and single crystal X-ray structure of N,N′-bis(diphenylphosphino)piperazine
Balakrishna, MS
George, PP
Mague, JT
JOURNAL OF CHEMICAL RESEARCH, 2003, (09) : 576 - 577
[24] Synthesis　and　X－ray　Structure　Analysis　of　Bis（carboethoxycyclopentadienyltricarbonylchromium）
Song Li-Cheng
Wang Ji-Quan
Hu Qing-Mei(Department of Chemistry
Wang Hong-Gen(Central Laboratory
结构化学, 1995, (01) : 15 - 19
[25] THE SYNTHESIS, COORDINATION AND ELECTROCHEMICAL STUDIES OF METALLOCENE BIS(CROWN ETHER) RECEPTOR MOLECULES - SINGLE-CRYSTAL X-RAY STRUCTURE OF A FERROCENE BIS(CROWN ETHER) POTASSIUM COMPLEX
BEER, PD
SIKANYIKA, H
SLAWIN, AMZ
WILLIAMS, DJ
POLYHEDRON, 1989, 8 (07) : 879 - 886
[26] 2,2-Bis(methoxy-NNO-azoxy)ethyl Derivatives of 4,8-Dihydro-bis-furazano[3,4-b:3′4′-e]pyrazine: The Synthesis and X-ray Investigation
Zyuzin, Igor N.
Suponitsky, Kyrill Yu.
Sheremetev, Aleksei B.
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2012, 49 (03) : 561 - 565
[27] Synthesis and X-ray crystal and molecular structure of 1,6-bis(3-thienyl)hexane
Chaloner, PA
Gunatunga, SR
Hitchcock, PB
JOURNAL OF CHEMICAL RESEARCH-S, 1997, (08): : 267 - &
[28] X-RAY DIFFRACTION INVESTIGATION OF CRYSTAL MOLECULAR STRUCTURE OF 3-NITRO-PHENYLHYDRAZONE-ACETONE
MENCZEL, G
ACTA CHIMICA ACADEMIAE SCIENTARIUM HUNGARICAE, 1969, 62 (01): : 41 - &
[29] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A TIN(IV) TETRAHALIDE ADDUCT WITH A CROWN ETHER
VALLE, G
CASSOL, A
RUSSO, U
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 82 (01): : 81 - 84
[30] Synthesis and X-ray single-crystal structure study of 5,5′-bis(silyl)-functionalized 3,3′-dibromo-2,2′-dithiophenes
Baumgartner, T
APPLIED ORGANOMETALLIC CHEMISTRY, 2005, 19 (07) : 859 - 863

← 1 2 3 4 5 →