Application of Liquid Gel Polymer Electrolyte Based on Chitosan-NH4NO3 for Proton Batteries

被引:11
作者
Jamaludin, A. [1 ]
Mohamad, A. A. [1 ]
机构
[1] Univ Sains Malaysia, Sch Mat & Mineral Resources Engn, Nibong Tebal 14300, Penang, Malaysia
关键词
polymer gel electrolytes; ionic conductivity; chitosan; ammonium nitrate; proton battery;
D O I
10.1002/app.32445
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Liquid gel polymer electrolyte (LGPE) based on chitosan, ammonium nitrate, and acetic acid with a ratio of 1.9 : 0.17 : 96.3 wt % gives the highest conductivity of (1.46 +/- 0.07) 10(-1) S cm(-1) at room temperature. This optimized composition of electrolyte is then used in proton batteries with the configuration of Zn + ZnSO4 center dot H2O/LGPE/MnO2. The open circuit voltage of battery is 1.41 V during 48 h of storage. The battery obtained a discharge capacity of 27.90 mA h(-1) upon discharge at 1.0 mA current. The maximum power density for the battery is 3.67 mW cm(-2). (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 118: 1240-1243, 2010
引用
收藏
页码:1240 / 1243
页数:4
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