A new 2D → 3D polycatenated Cd(II) coordination polymer: Syntheses, structure and luminescent sensing

被引：9

作者：

Yuan, Fei ^{[1
,2
]}

Yuan, Chun-Mei ^{[1
]}

Hu, Huai-Ming ^{[2
]}

Liang, Yuan-Yuan ^{[2
]}

Wang, Xiaofang ^{[2
]}

Zhou, Chun-Sheng ^{[1
]}

机构：

[1] Shangluo Univ, Coll Chem Engn & Modern Mat, Shaanxi Key Lab Comprehens Utilizat Tailings Reso, Shangluo 726000, Peoples R China

[2] Northwest Univ, Coll Chem & Mat Sci, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian 710127, Shaanxi, Peoples R China

来源：

POLYHEDRON | 2018年 / 155卷

关键词：

Coordination polymer; Carboxylate ligand; Luminescence sensor; Solvothermal synthesis; Topology;

D O I：

10.1016/j.poly.2018.08.048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D coordination polymer, [NH2(CH3)(2)](n)[Cd(TCBPA)](n)center dot 3nH(2)O (1) {H(3)TCBPA = tris[(4-carboxyl)-phenylduryl]amine}, was constructed under solvothermal conditions and structurally characterized by elemental analysis, FT-IR spectroscopy, powder X-ray diffraction (PXPD) and thermogravimetric analysis (TGA). Single crystal X-ray diffraction indicates that compound 1 displays a uninodal 3-connected 2D -> 3D polycatenated network with the point symbol of 6(3). Furthermore, photoluminescence of 1 was investigated and has been successfully applied in the detection of Fe3+ ion in DMF solution. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：268 / 274

页数：7

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