Universal approach to quantum thermodynamics of strongly coupled systems under nonequilibrium conditions and external driving

被引:20
作者
Dou, Wenjie [1 ]
Baetge, Jakob [2 ]
Levy, Amikam [1 ,3 ]
Thoss, Michael [2 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Freiburg, Inst Phys, Hermann Herder Str 3, D-79104 Freiburg, Germany
[3] Tel Aviv Univ, Raymond & Beverly Sackler Ctr Computat Mol & Mat, IL-69978 Tel Aviv, Israel
关键词
TIME-DEPENDENT HARTREE; HEAT;
D O I
10.1103/PhysRevB.101.184304
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present an approach based on a density matrix expansion to study thermodynamic properties of a quantum system strongly coupled to two or more baths. For slow external driving of the system, we identify the adiabatic and nonadiabatic contributions to thermodynamic quantities, and we show how the first and second laws of thermodynamics are manifested in the strong coupling regime. Particularly, we show that the entropy production is positive up to second order in the driving speed. The formulation can be applied both for bosonic and fermionic systems, and recovers previous results for the equilibrium case [Phys. Rev. B 98, 134306 (2018)]. The approach is then demonstrated for the driven resonant level model as well as the driven Anderson impurity model, where the hierarchical quantum master equation method is used to accurately simulate the nonequilibrium quantum dynamics.
引用
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页数:10
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