[(η5-C5Me4CH2R)Ru(η6-arene)]+ and [η5-C5Me4CH2R)Ru(CH3CN)3]+ compounds possessing pendant arms

被引：23

作者：

Fairchild, Robert M. ^{[1
]}

Holman, K. Travis ^{[1
]}

机构：

[1] Georgetown Univ, Dept Chem, Washington, DC 20057 USA

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 08期

关键词：

D O I：

10.1021/om701084m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(eta(5)-C5Me4CH2)Ru(eta(6)-arene)](+) , [eta(5)-C5Me4CH2R)Ru(CH3CN)(3)](+) (R = OH, OR, and NR1R2), and related compounds possessing pendant arms are synthesized by the attack of water, alcohol, alkoxide, or amine nucleophiles on the methylenic carbon atoms of the readily available tetramethylfulvene complex [(eta(6)-C5Me4CH2)(RuCl)-Cl-11(mu-Cl)](2) (1) or its simple acetonitrile derivative, [(eta(6)-C5Me4CH2)Ru-11(CH3CN)Cl-2] (1a). The [(eta(5)-C5Me4CH2R)Ru (eta(6)-arene)](+) compounds can generally be quantitatively converted back into [(eta(5)-C5Me4CH2R)Ru(CH3CN)(3)](+) species by UV photolysis in CH3CN.

引用

页码：1823 / 1833

页数：11

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