TiCl4-catalyzed intermolecular hydroamination reactions

被引：102
作者：
Ackermann, L [1 ]
机构：
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源：
ORGANOMETALLICS | 2003年 / 22卷 / 22期
关键词：
D O I：
10.1021/om034143g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A user-friendly procedure for intermolecular hydroamination reactions is presented which employs inexpensive and readily available TiCl4. Through addition of (BuNH2)-Bu-t, a novel catalytic system is generated which enables the efficient conversion of aminoallenes, as well as variously substituted internal and terminal alkynes.
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收藏
页码：4367 / 4368
页数：2
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