Group 4 metal initiators for the controlled stereoselective polymerization of lactide monomers

被引：60

作者：

Buffet, Jean-Charles ^{[1
]}

Okuda, Jun ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, Landoltweg 1, D-52056 Aachen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 16期

关键词：

RING-OPENING POLYMERIZATION; RACEMIC LACTIDE; SALEN-ALUMINUM; MESO-LACTIDE; RAC-LACTIDE; COMPLEXES; LIGAND; ALKOXIDE; MAGNESIUM; TITANIUM;

D O I：

10.1039/c1cc10149h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Group 4 metal initiators with a tetradentate bis(phenolato) ligand polymerized meso-lactide efficiently under ring-opening to give syndiotactic polylactide. L-Lactide was converted faster than rac-lactide and meso-lactide.

引用

页码：4796 / 4798

页数：3

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