Synthesis and crystal structure of a novel coordination polymer, {[Cd2(N2H4)6][Cd(N2H4)3](NO3)6}n, based on the μ-bridging mode of hydrazine

被引：0

作者：

Asenjan, Afrouz Khadivi ^{[1
]}

Alemi, Abdolali ^{[1
]}

Gable, Robert W. ^{[2
]}

机构：

[1] Univ Tabriz, Dept Inorgan Chem, Fac Chem, Tabriz, Iran

[2] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2021年 / 1244卷

关键词：

Single crystal; Coordination polymer; Cadmium; Hydrazine; TRANSITION-METAL-COMPLEXES; CADMIUM CHLORIDE; GROWTH; NITRATE; REACTIVITY; SPECTRUM; LIGANDS;

D O I：

10.1016/j.molstruc.2021.130882

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Micro dimensional hexagonal prisms of {[Cd-2(N2H4)(6)][Cd(N2H4)(3)](NO3)(6)}(n) were crystallized in trigonal crystal system with space group of P31c. The crystal structure shows the compound to be comprised of linear chains of cadmium atoms octahedrally coordinated by six bridging N2H4 ligands. The compound was characterized by a number of techniques including X-ray Powder Diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), FT-IR, and scanning electron microscopy (SEM). The UV-Vis absorption spectrum shows a wide transparency range suggesting that the compound may be a prospective candidate for nonlinear optical applications. (C) 2021 Published by Elsevier B.V.

引用

页数：8

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