Chiral electronic transitions of YVO4:Eu3+ nanoparticles in cellulose based photonic materials with circularly polarized excitation

被引:63
作者
Chu, Guang [1 ]
Wang, Xuesi [2 ]
Chen, Tianrui [1 ]
Xu, Wen [2 ]
Wang, Yu [1 ]
Song, Hongwei [2 ]
Xu, Yan [1 ]
机构
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[2] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
MESOPOROUS SILICA; IONIC-STRENGTH; NEMATIC PHASE; LUMINESCENCE; FILMS; PHOTOLUMINESCENCE; NANOCOMPOSITES; NANOCRYSTALS; SUSPENSIONS; DICHROISM;
D O I
10.1039/c4tc02913e
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel chiral nematic luminescent film is fabricated by incorporating YVO4:Eu3+ nanoparticles with cellulose nanocrystals. We have shown that these nanoparticles could attach to the surface of twisted nanorods of cellulose, exhibiting electronic transition-based hierarchical chiroptical activity, responsible for strong circularly polarized emission and a high luminescence polarization dissymmetry factor.
引用
收藏
页码:3384 / 3390
页数:7
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