Monomer reactivity ratios and Q,e-values of trialkylsilyl acrylates and methacrylates

被引：3

作者：

Fujiwara, H ^{[1
]}

Narita, T ^{[1
]}

Hamana, H ^{[1
]}

机构：

[1] Saitama Inst Technol, Dept Appl Chem, Okabe, Saitama 3690293, Japan

来源：

POLYMER JOURNAL | 2001年 / 33卷 / 01期

关键词：

monomer reactivity ratios; Q; e; tributylsilyl methacrylate; tri(iso-propyl)silyl methacrylate; tri(iso-butyl) silyl methacrylate; tributylsilyl acrylate; tri-(iso-propyl)silyl acrylate;

D O I：

10.1295/polymj.33.102

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The monomer reactivity ratio and Q, e of trialkylsilyl methacrylates and acrylates were studied. Copolymerizations of trialkylsilyl acrylates and methacrylates (M1) with styrene (M2) were carried out in bulk with sealed tube under nitrogen atmosphere at 80°C initiated by BPO. Copolymer composition of each monomer unit in copolymer was obtained from 1H NMR measurement. Monomer reactivity ratios were determined by the Kelen-Tudos method.

引用

页码：102 / 103

页数：2

共 4 条

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