Multi-walled carbon nanotubes-cellulose paper for a chemical vapor sensor

被引:93
作者
Yun, Sungryul [1 ]
Kim, Jaehwan [1 ]
机构
[1] Inha Univ, Dept Mech Engn, Ctr EAPap Actuator, Inchon 402751, South Korea
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2010年 / 150卷 / 01期
关键词
Cellulose; MWCNTs; Covalent bonds; Solvent vapor; Chemical sensor; Relative resistance response; ELECTROACTIVE PAPER;
D O I
10.1016/j.snb.2010.06.068
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper reports the multi-walled carbon nanotubes (MWCNTs)-cellulose paper as a chemical vapor sensor Cellulose solution was prepared by dissolving cotton pulp in LiCl/N,N-dimerhylacetamide solution MWCNTs were covalently grafted to cellulose by reacting imidazolides-MWCNTs with cellulose solution Using this product. the MWCNTs/cellulose (M/C) paper was fabricated. followed by mechanical stretching to align MWCNTs with cellulose chains Characteristics of the M/C paper were analyzed in terms of scanning electron microscope images, Young's modulus and electrical resistance The M/C paper was investigated as a chemical sensor that can detect vaporized analyte molecules, such as, methanol, ethanol, 1-butanol and 1-propanol Their electrical responses on the sensor were evaluated by not only comparing their relative resistance response (A(R)) depending on the concentration, but also checking signal revel sibility under cyclic exposure of each analyte Due to sensitive and reversible expansion/contraction of the M/C paper in response to analytes. the M/C paper showed reversible and fast response with the following rank of A(R) methanol < ethanol < 1-propanol < 1-butanol Especially, the linear response to 1-propanol concentration proved that the M/C paper can be a qualified sensor for n-propanol (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码:308 / 313
页数:6
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