Metal salt-catalyzed diazocoupling of 3-substituted-1H-pyrazol-2-in-5-ones in aqueous medium

被引:30
作者
Khalil, AK [1 ]
Hassan, MA [1 ]
Mohamed, MM [1 ]
El-Sayed, AM [1 ]
机构
[1] Ain Shams Univ, Fac Sci, Dept Chem, Cairo, Egypt
关键词
AlCl3-catalyst; diazocoupling in water; 3-substituted-1H-pyrazol-2-in-5-ones;
D O I
10.1016/j.dyepig.2004.10.005
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Organic synthesis in water belongs to green chemistry. AlCl3-catalyzed diazocoupling of 3-substituted-1 H-pyrazol-2-in-5-ones (1) in water with different aryldiazonium salts yielded (5-hydroxy-3-substituted-1H-pyrazol-4-yl)-azobenzene derivatives (2) as colored products with high yields. (c) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:241 / 245
页数:5
相关论文
共 31 条
[1]   Bromolysis and iodolysis of α,β-epoxycarboxylic acids in water catalyzed by indium halides [J].
Amantini, D ;
Fringuelli, F ;
Pizzo, F ;
Vaccaro, L .
JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (13) :4463-4467
[2]   Synthesis and characterization of new 3,5-dinaphthyl substituted 2-pyrazolines and study of their antimicrobial activity [J].
Azarifar, D ;
Shaebanzadeh, M .
MOLECULES, 2002, 7 (12) :885-895
[3]  
DHAL PN, 1975, J INDIAN CHEM SOC, V52, P1196
[4]   PECULIAR C-C BOND CLEAVAGES OF PYRAZOLYL PROPENONE EPOXIDES INDUCED BY GRIGNARD-REAGENTS [J].
ELSHEKEIL, A ;
BABAQI, A ;
HASSAN, M ;
SHIBA, S .
HETEROCYCLES, 1988, 27 (11) :2577-2580
[5]   Synthesis of some hetarylazopyrazolone dyes and solvent effects on their absorption spectra [J].
Ertan, N .
DYES AND PIGMENTS, 1999, 44 (01) :41-48
[6]   Zn(II)-catalyzed thiolysis of oxiranes in water under neutral conditions [J].
Fringuelli, F ;
Pizzo, F ;
Tortoioli, S ;
Vaccaro, L .
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (21) :8248-8251
[7]   Indium salt-promoted organic reactions [J].
Fringuelli, F ;
Piermatti, O ;
Pizzo, F ;
Vaccaro, L .
CURRENT ORGANIC CHEMISTRY, 2003, 7 (16) :1661-1689
[8]   AlCl3 as an efficient Lewis acid catalyst in water [J].
Fringuelli, F ;
Pizzo, F ;
Vaccaro, L .
TETRAHEDRON LETTERS, 2001, 42 (06) :1131-1133
[9]  
Fringuelli F., 2002, The Diels-Alder Reaction: Selected Practical Methods
[10]  
FRINGUELLI F, 2002, ADV SYNTH CATAL, P344