Crystallization of Covalent Organic Frameworks for Gas Storage Applications

被引：148

作者：

Zhu, Lijuan ^{[1
]}

Zhang, Yue-Biao ^{[1
]}

机构：

[1] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China

来源：

MOLECULES | 2017年 / 22卷 / 07期

基金：

中国国家自然科学基金;

关键词：

covalent organic framework; crystallization; dynamic covalent chemistry; hydrogen storage; methane storage; CO2; capture; TRIAZINE-BASED FRAMEWORKS; HIGHLY CRYSTALLINE; ROOM-TEMPERATURE; HYDROGEN-BONDS; CARBON-DIOXIDE; PORE SURFACE; FLUORESCENT; STABILITY; CHEMISTRY; LINKAGES;

D O I：

10.3390/molecules22071149

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Covalent organic frameworks (COFs) have emerged as a new class of crystalline porous materials prepared by integrating organic molecular building blocks into predetermined network structures entirely through strong covalent bonds. The consequently encountered "crystallization problem" has been conquered by dynamic covalent chemistry in syntheses and reticular chemistry in materials design. In this contribution, we have reviewed the progress in the crystallization of COF materials and their hydrogen, methane and carbon dioxide gas storage properties for clean energy applications.

引用

页数：29

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