Multifunctional Polyacrylonitrile-ZnO/Ag Electrospun Nanofiber Membranes with Various ZnO Morphologies for Photocatalytic, UV-shielding, and Antibacterial Applications

被引:58
作者
Chen, Yen-Yu [1 ]
Kuo, Chi-Ching [1 ]
Chen, Bo-Yu [1 ]
Chiu, Pei-Chi [1 ]
Tsai, Ping-Chun [1 ]
机构
[1] Natl Taipei Univ Technol, Inst Organ & Polymer Mat, Taipei 10608, Taiwan
关键词
antibacterial; electrospinning; fibers; morphology; photocatalysis; nanotechnology; UV-shielding; COMPOSITE NANOFIBERS; FIBERS; GROWTH; TEXTILES; POLYMER;
D O I
10.1002/polb.23621
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
New multifunctional polyacrylonitrile (PAN)-ZnO/Ag composite electrospun nanofiber membranes consisting of pineal-type, flower-type, and sea-urchin-type ZnO morphologies were prepared using a single-capillary electrospinning technique, hydrothermal ZnO synthesis, and Ag reduction. The various ZnO architectures exhibited differences in photocatalytic activity and UV-shielding efficiency, and were ranked as follows: sea-urchin type>flower type>pineal type. Sea-urchin-type ZnO features a higher surface-to-volume ratio than other ZnO architectures do because of its distinctive structure, thus yielding higher performance. The present study demonstrated that self-standing PAN-ZnO/Ag composite fiber membranes, especially those with the sea-urchin-type ZnO structure, can be applied in multifunctional textiles such as water purification filters and antibacterial and UV-shielding clothes. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015, 53, 262-269
引用
收藏
页码:262 / 269
页数:8
相关论文
共 37 条
[1]  
ALESSIO B, 2007, J NANOPART RES, V10, P679
[2]   Synthesis, Morphology, and Sensory Applications of Multifunctional Rod-Coil-Coil Triblock Copolymers and Their Electrospun Nanofibers [J].
Chiu, Yu-Cheng ;
Chen, Yougen ;
Kuo, Chi-Ching ;
Tung, Shih-Huang ;
Kakuchi, Toyoji ;
Chen, Wen-Chang .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (07) :3387-3395
[3]   Morphology-controlled growth of ZnO nanostructures using microwave irradiation: from basic to complex structures [J].
Cho, Seungho ;
Jung, Seung-Ho ;
Lee, Kun-Hong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (33) :12769-12776
[4]   Precursor Effects of Citric Acid and Citrates on ZnO Crystal Formation [J].
Cho, Seungho ;
Jang, Ji-Wook ;
Jung, Seung-Ho ;
Lee, Bo Ram ;
Oh, Eugene ;
Lee, Kun-Hong .
LANGMUIR, 2009, 25 (06) :3825-3831
[5]   Highly efficient inorganic transparent UV-protective thin-film coating by low temperature sol-gel procedure for application on heat-sensitive substrates [J].
Cui, Hongtao ;
Zayat, Marcos ;
Garcia Parejo, Pilar ;
Levy, David .
ADVANCED MATERIALS, 2008, 20 (01) :65-+
[6]   UV-protection properties of electrospun polyacrylonitrile nanofibrous mats embedded with MgO and Al2O3 nanoparticles [J].
Dadvar, Saeed ;
Tavanai, Hossein ;
Morshed, Mohammad .
JOURNAL OF NANOPARTICLE RESEARCH, 2011, 13 (10) :5163-5169
[7]   UV-protection and photocatalytic properties of electrospun polyacrylonitrile nanofibrous mats coated with TiO2 nanofilm via sol-gel [J].
Dadvar, Saeed ;
Tavanai, Hossein ;
Dadvar, Hamid ;
Morshed, Mohammad ;
Ghodsi, Farhad E. .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2011, 59 (02) :269-275
[8]   Nucleation and growth of anatase crystallites on cotton fabrics at low temperatures [J].
Daoud, WA ;
Xin, JH .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2004, 87 (05) :953-955
[9]   Morphology and Photocatalytic Property of Hierarchical Polyimide/ZnO Fibers Prepared via a Direct Ion-exchange Process [J].
Ding, Qianwei ;
Miao, Yue-E ;
Liu, Tianxi .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (12) :5617-5622
[10]  
Farid J. S., 2012, CERAM INT, V38, P3649