N-fused carbazole-zinc porphyrin-free-base porphyrin triad for efficient near-IR dye-sensitized solar cells

被引:93
作者
Liu, Yizhu [1 ,2 ]
Lin, Hong [2 ]
Dy, Joanne Ting [1 ]
Tamaki, Koichi [1 ]
Nakazaki, Jotaro [1 ]
Nakayama, Daisuke [1 ]
Uchida, Satoshi [1 ]
Kubo, Takaya [1 ]
Segawa, Hiroshi [1 ]
机构
[1] Univ Tokyo, Res Ctr Adv Sci & Technol, Meguro Ku, Tokyo 1538904, Japan
[2] Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
关键词
EXCITED-STATES; ORGANIC-DYES; DYNAMICS; SINGLET; RECOMBINATION; DESIGN;
D O I
10.1039/c0cc03306e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
N-fused carbazole-zinc porphyrin-free-base porphyrin triad featuring an ethynyl-linkage was synthesized; efficient sensitization as long as 900 nm was demonstrated and an overall light-to-electricity conversion effciency of 5.21% was achieved under AM 1.5 G one sun illumination.
引用
收藏
页码:4010 / 4012
页数:3
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