3-methyl-1,2,3-butanetricarboxylic acid:: An atmospheric tracer for terpene secondary organic aerosol

被引：236

作者：

Szmigielski, Rafal ^{[1
]}

Surratt, Jason D. ^{[2
]}

Gomez-Gonzalez, Yadian ^{[1
]}

Van der Veken, Pieter ^{[1
]}

Kourtchev, Ivan ^{[1
]}

Vermeylen, Reinhilde ^{[1
]}

Blockhuys, Frank ^{[3
]}

Jaoui, Mohammed ^{[4
]}

Kleindienst, Tadeusz E. ^{[5
]}

Lewandowski, Michael ^{[5
]}

Offenberg, John H. ^{[5
]}

Edney, Edward O. ^{[5
]}

Seinfeld, John H. ^{[6
,7
]}

Maenhaut, Willy ^{[8
]}

Claeys, Magda ^{[1
]}

机构：

[1] Univ Antwerp, Dept Pharmaceut Sci, BE-2610 Antwerp, Belgium

[2] CALTECH, Dept Chem, Pasadena, CA 91125 USA

[3] Univ Antwerp, Dept Chem, BE-2610 Antwerp, Belgium

[4] Alion Sci & Technol, Res Triangle Pk, NC USA

[5] US EPA, Off Res & Dev, Natl Exposure Res Lab, Res Triangle Pk, NC 27711 USA

[6] CALTECH, Dept Chem Engn, Pasadena, CA 91125 USA

[7] CALTECH, Dept Environm Sci & Engn, Pasadena, CA 91125 USA

[8] Univ Ghent, Inst Nucl Sci, Analyt Chem Lab, BE-9000 Ghent, Belgium

来源：

GEOPHYSICAL RESEARCH LETTERS | 2007年 / 34卷 / 24期

关键词：

PARTICULATE PRODUCTS; ALPHA-PINENE; OXIDATION; MONOTERPENES; PHOTOOXIDATION; FOREST; ISOPRENE; YIELDS; PM2.5; NOX;

D O I：

10.1029/2007GL031338

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

Highly oxygenated compounds assigned to be oxidation products of alpha-pinene have recently been observed in substantial concentrations in ambient aerosols. Here, we confirm the unknown alpha- pinene tracer compound with molecular weight (MW) 204 as the C-8-tricarboxylic acid 3-methyl-1,2,3-butanetricarboxylic acid. Its gas and liquid chromatographic behaviors and its mass spectral characteristics in electron ionization and negative ion electrospray ionization perfectly agree with those of a synthesized reference compound. The formation of this compound is explained by further reaction of cis-pinonic acid involving participation of the OH radical. This study illustrates that complex, multi-generation chemistry holds for the photooxidation of alpha-pinene in the presence of NOx.

引用

页数：6

共 24 条

[11] NH3 Weakens the Enhancing Effect of SO2 on Biogenic Secondary Organic Aerosol Formation [J].

Du, Lin ;

Xu, Li ;

Li, Kun ;

George, Christian ;

Ge, Maofa .

ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS, 2023, 10 (02) :145-151

[12] Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal [J].

Shalamzari, Mohammad Safi ;

Vermeylen, Reinhilde ;

Blockhuys, Frank ;

Kleindienst, Tadeusz E. ;

Lewandowski, Michael ;

Szmigielski, Rafal ;

Rudzinski, Krzysztof J. ;

Spolnik, Grzegorz ;

Danikiewicz, Witold ;

Maenhaut, Willy ;

Claeys, Magda .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2016, 16 (11) :7135-7148

[13] Reaction Kinetics and Secondary Organic Aerosol Composition Analysis of 2-Cyclohexen-1-one with NO3 Radicals [J].

Hu, Lin ;

Tong, Shengrui ;

Xu, Yanyong ;

Zhang, Hailiang ;

Yu, Shanshan ;

Chen, Meifang ;

Ge, Maofa .

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2024, 40 (04) :675-681

[14] Synergetic formation of secondary inorganic and organic aerosol: effect of SO2 and NH3 on particle formation and growth [J].

Chu, Biwu ;

Zhang, Xiao ;

Liu, Yongchun ;

He, Hong ;

Sun, Yele ;

Jiang, Jingkun ;

Li, Junhua ;

Hao, Jiming .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2016, 16 (22) :14219-14230

[15] Effects of seed particles Al2O3, Al2(SO4)3 and H2SO4 on secondary organic aerosol [J].

Zhang, Xiao ;

Chu, Biwu ;

Li, Junhua ;

Zhang, Chaozhi .

FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING, 2017, 11 (04)

[16] The roles of individual oxidants in secondary organic aerosol formation from Δ3-carene:: 2.: soa formation and oxidant contribution [J].

Colville, CJ ;

Griffin, RJ .

ATMOSPHERIC ENVIRONMENT, 2004, 38 (24) :4013-4023

[17] Formation of 2-methyl tetrols and 2-methylglyceric acid in secondary organic aerosol from laboratory irradiated isoprene/NOX/SO2/air mixtures and their detection in ambient PM2.5 samples collected in the eastern United States [J].

Edney, EO ;

Kleindienst, TE ;

Jaoui, M ;

Lewandowski, M ;

Offenberg, JH ;

Wang, W ;

Claeys, M .

ATMOSPHERIC ENVIRONMENT, 2005, 39 (29) :5281-5289

[18] Similarities in STXM-NEXAFS Spectra of Atmospheric Particles and Secondary Organic Aerosol Generated from Glyoxal, α-Pinene, Isoprene, 1,2,4-Trimethylbenzene, and d-Limonene [J].

Shakya, Kabindra M. ;

Liu, Shang ;

Takahama, Satoshi ;

Russell, Lynn M. ;

Keutsch, Frank N. ;

Galloway, Melissa M. ;

Shilling, John E. ;

Hiranuma, Naruki ;

Song, Chen ;

Kim, Hwajin ;

Paulson, Suzanne E. ;

Pfaffenberger, Lisa ;

Barmet, Peter ;

Slowik, Jay ;

Prevot, Andre S. H. ;

Dommen, Josef ;

Baltensperger, Urs .

AEROSOL SCIENCE AND TECHNOLOGY, 2013, 47 (05) :543-555

[19] Effects of NOx and SO2 on the secondary organic aerosol formation from the photooxidation of 1,3,5-trimethylbenzene: A new source of organosulfates [J].

Yang, Zhaomin ;

Tsona, Narcisse T. ;

Li, Jianlong ;

Wang, Shuyan ;

Xu, Li ;

You, Bo ;

Du, Lin .

ENVIRONMENTAL POLLUTION, 2020, 264

[20] Characterization of 2-methylglyceric acid oligomers in secondary organic aerosol formed from the photooxidation of isoprene using trimethylsilylation and gas chromatography/ion trap mass spectrometry [J].

Szmigielski, Rafal ;

Surratt, Jason D. ;

Vermeylen, Reinhilde ;

Szmigielska, Katarzyna ;

Kroll, Jesse H. ;

Ng, Nga L. ;

Murphy, Shane M. ;

Sorooshian, Armin ;

Seinfeld, John H. ;

Claeys, Magda .

JOURNAL OF MASS SPECTROMETRY, 2007, 42 (01) :101-116

← 1 2 3 →