Critical Challenges in Rechargeable Aprotic Li-O2 Batteries

被引：380
作者：
Feng, Ningning [2 ]
He, Ping [1 ,2 ]
Zhou, Haoshen [1 ,2 ,3 ]
机构：
[1] Nanjing Univ, Coll Engn & Appl Sci, Ctr Energy Storage Mat & Technol, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[3] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Umezono 1-1-1, Tsukuba, Ibaraki 3058568, Japan
来源：
ADVANCED ENERGY MATERIALS | 2016年 / 6卷 / 09期
基金：
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词：
LITHIUM-OXYGEN BATTERIES; LI-AIR BATTERIES; HIGH-PERFORMANCE CATHODE; REDUCED GRAPHENE OXIDE; IN-SITU; BIFUNCTIONAL CATALYST; DIMETHYL-SULFOXIDE; ELECTROCHEMICAL PERFORMANCE; ALPHA-MNO2; NANORODS; EVOLUTION REACTIONS;
D O I：
10.1002/aenm.201502303
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Rechargeable aprotic Li-O-2 batteries are one of the most promising next-generation battery technologies that can deliver extremely high energy density. In the past decades, this technology has attracted worldwide attention, and considerable progress has been achieved. However, numerous critical scientific challenges remain to be solved for practical applications. A specific discussion of recent progress from the perspective of the stable aprotic Li-O-2 system with high energy efficiency is presented. The discussion is highlighted on the reaction mechanisms on air cathode, stability of cell components in semi-open surroundings, and improvement of battery performance by catalyst design. Challenges and perspectives are also presented. This study provides an intensive understanding of aprotic Li-O-2 batteries and offers an important guideline for developing reversible and high-efficiency Li-O-2 batteries.
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页数：24
相关论文
共 177 条
[1]   A polymer electrolyte-based rechargeable lithium/oxygen battery [J].
Abraham, KM ;
Jiang, Z .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :1-5
[2]   The Importance of Nanometric Passivating Films on Cathodes for Li-Air Batteries [J].
Adams, Brian D. ;
Black, Robert ;
Radtke, Claudio ;
Williams, Zack ;
Mehdi, B. Layla ;
Browning, Nigel D. ;
Nazar, Linda F. .
ACS NANO, 2014, 8 (12) :12483-12493
[3]   Towards a Stable Organic Electrolyte for the Lithium Oxygen Battery [J].
Adams, Brian D. ;
Black, Robert ;
Williams, Zack ;
Fernandes, Russel ;
Cuisinier, Marine ;
Berg, Erik Jaemstorp ;
Novak, Petr ;
Murphy, Graham K. ;
Nazar, Linda F. .
ADVANCED ENERGY MATERIALS, 2015, 5 (01)
[4]   Current density dependence of peroxide formation in the Li-O2 battery and its effect on charge [J].
Adams, Brian D. ;
Radtke, Claudio ;
Black, Robert ;
Trudeau, Michel L. ;
Zaghib, Karim ;
Nazar, Linda F. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1772-1778
[5]  
Aetukuri NB, 2015, NAT CHEM, V7, P50, DOI [10.1038/NCHEM.2132, 10.1038/nchem.2132]
[6]   Oxygen Reduction Reactions in Ionic Liquids and the Formulation of a General ORR Mechanism for Li-Air Batteries [J].
Allen, Chris J. ;
Hwang, Jaehee ;
Kautz, Roger ;
Mukerjee, Sanjeev ;
Plichta, Edward J. ;
Hendrickson, Mary A. ;
Abraham, K. M. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (39) :20755-20764
[7]   Oxygen Electrode Rechargeability in an Ionic Liquid for the Li-Air Battery [J].
Allen, Chris J. ;
Mukerjee, Sanjeey ;
Plichta, Edward J. ;
Hendrickson, Mary A. ;
Abraham, K. M. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2011, 2 (19) :2420-2424
[8]   Understanding the Chemical Stability of Polymers for Lithium-Air Batteries [J].
Amanchukwu, Chibueze V. ;
Harding, Jonathon R. ;
Shao-Horn, Yang ;
Hammond, Paula T. .
CHEMISTRY OF MATERIALS, 2015, 27 (02) :550-561
[9]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[10]   Interactions of Dimethoxy Ethane with Li2O2 Clusters and Likely Decomposition Mechanisms for Li-O2 Batteries [J].
Assary, Rajeev S. ;
Lau, Kah Chun ;
Amine, Khalil ;
Sun, Yang-Kook ;
Curtiss, Larry A. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (16) :8041-8049
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