Preparation and spectroscopic characterization of perfluoro(isopropyl)-trifluoroacetylperoxide (CF3)2C(F)OOC(O)CF3

被引：0

作者：

Minkwitz, R ^{[1
]}

Reinemann, S ^{[1
]}

机构：

[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 10期

关键词：

perfluoro(isopropyl)trifluoroacetylperoxid; oxygendifluoride; peroxides; vibrational spectra; NMR spectra;

D O I：

10.1002/(SICI)1521-3749(199810)624:10<1695::AID-ZAAC1695>3.0.CO;2-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of perfluoroacetone (CF3)(2)CO with OF2 in a ratio 2:1 yields Perfluoro (isopropyl)-trifluoroacetylperoxide (CF3)(2)C(F)OOC(O)CF3. The reaction only occurs under CsF-catalysis. (CF3)(2)C(F)OOC(O)CF3 is characterized by vibrational, nmr and mass spectra. Using an excess of OF2 does not give any stable product.

引用

页码：1695 / 1698

页数：4

共 27 条

[21] Reactive E=C(p-p)-pi systems .43. Synthesis and characterization of P-phosphino or P-arsino substituted fluorophosphaalkenes of the type R(2)E-P=C(F)NEt(2) (R=Me, CF3,Me(2)N; E=P, As)
Grobe, J
LeVan, D
Winnemoller, J
Krebs, B
Lage, M
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (06): : 778 - 784
[22] On the preparation, spectroscopic characterization and crystal structure of trifluoromethylazosulfon-N,N-dimethylamide (CH3)(2)NS(O)(2)NNCF3
Minkwitz, R
Jakob, J
Kornath, A
Preut, H
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (04): : 557 - 562
[23] Vibrational studies of N-trifluoroacetyl-phosphoramidic acid dichloride [CF3C(O)NHP(O)Cl2] and N-trichloroacetyl-phosphoramidic acid dichloride [CCl3C(O)NHP(O)Cl2]
Iriarte, Ana G.
Cutin, Edgardo H.
Erben, Mauricio F.
Ulic, Sonia E.
Jios, Jorae L.
Della Vedova, Carlos O.
[J]. VIBRATIONAL SPECTROSCOPY, 2008, 46 (02) : 107 - 114
[24] PREPARATION AND SPECTROSCOPIC CHARACTERIZATION OF THE FLUOROPHOSPHONIUM SALTS X2FPSCH3+MF6- (X = BR, CL M = AS, SB) AND XF2PSCH3+SBF6- (X = BR, CL, F)
MINKWITZ, R
GARZAREK, P
MEDGER, G
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 612 (06): : 40 - 44
[25] On the chemistry of fluoroorgano derivatives of group 13 elements.: 1 -: The reactions of perfluoroiodoalkanes and pentafluoroiodobenzene with triethylindium -: Synthesis and characterization of In(C2H5)2(C6F5)•N(C2H5)3 and In(C2H5)2(i-C3F7)•N(C2H5)3 and spectroscopic evidence for bis(3,3,4,4,4-pentafluorobutyl)indium iodide
Choi, ZH
Tyrra, W
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (12): : 2015 - 2020
[26] Preparation, spectral characterization, crystal structure, thermal analysis I and Hirshfeld surface analysis of the complex [Co(H2O)3(SCN)2(C5H8N2)]-3(C8H10N4O2),1.25H2O
EL Hamdani, H.
EL Amane, M.
Duhayon, C.
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 111
[27] The effect of various substituents on the structural parameters of the P(O)[N(CH3)(CH2C6H5)]2 moiety.: Syntheses and spectroscopic characterization of some new phosphoramidates, crystal structures of P(O)(X)[N(CH3)(CH2C6H5)]2, X = C6H5C(O)NH, Cl and CCl3C(O)NH
Gholivand, K
Pourayoubi, M
Shariatinia, Z
Mostaanzadeh, H
[J]. POLYHEDRON, 2005, 24 (05) : 655 - 662

← 1 2 3 →