Preparation and spectroscopic characterization of perfluoro(isopropyl)-trifluoroacetylperoxide (CF3)2C(F)OOC(O)CF3

被引：0

作者：

Minkwitz, R ^{[1
]}

Reinemann, S ^{[1
]}

机构：

[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 10期

关键词：

perfluoro(isopropyl)trifluoroacetylperoxid; oxygendifluoride; peroxides; vibrational spectra; NMR spectra;

D O I：

10.1002/(SICI)1521-3749(199810)624:10<1695::AID-ZAAC1695>3.0.CO;2-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of perfluoroacetone (CF3)(2)CO with OF2 in a ratio 2:1 yields Perfluoro (isopropyl)-trifluoroacetylperoxide (CF3)(2)C(F)OOC(O)CF3. The reaction only occurs under CsF-catalysis. (CF3)(2)C(F)OOC(O)CF3 is characterized by vibrational, nmr and mass spectra. Using an excess of OF2 does not give any stable product.

引用

页码：1695 / 1698

页数：4

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