Gas-phase conversion of tetramethoxysilane to trimethoxysilane

被引：2
|
作者：
Kojima, T
Uchiyama, T
Murata, D
Kato, S
Watanabe, Y
Shibuya, H
机构：
[1] Seikei Univ, Dept Appl Chem, Tokyo 1808633, Japan
[2] JGC Corp, Res & Dev Div, Ibaraki 3111313, Japan
来源：
KAGAKU KOGAKU RONBUNSHU | 2005年 / 31卷 / 02期
关键词：
gas-phase conversion; copper catalysis; tetramethoxysilane; trimethoxysilane; silicon;
D O I：
10.1252/kakoronbunshu.31.115
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The possibility of gas-phase conversion of tetramethoxysilane to trimethoxysilane was thermodynamically and experimentally evaluated. Tetramethoxysilane is a byproduct of a proposed process for production of poly-crystalline silicon from trimethoxysilane without using chlorine compounds. It was found that a trimethoxysilane yield of more than one percent is possible under conditions of 0.1 MPa and 1023 K with a Si-Cu catalyst.
引用
收藏
页码：115 / 117
页数：3
相关论文
共 50 条
  • [1] Gas-phase synthesis of fine silica particles from tetramethoxysilane
    Kojima, T
    Uchiyama, T
    Katou, S
    Shibuya, H
    Uemiya, S
    KAGAKU KOGAKU RONBUNSHU, 2004, 30 (03) : 306 - 310
  • [2] High-temperature gas-phase kinetics of the thermal decomposition of tetramethoxysilane
    Sela, P.
    Peukert, S.
    Herzler, J.
    Sakai, Y.
    Fikri, M.
    Schulz, C.
    PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2019, 37 (01) : 1133 - 1141
  • [3] MOLECULAR-STRUCTURE OF TETRAMETHOXYSILANE IN GAS-PHASE, AN ELECTRON-DIFFRACTION STUDY
    BOONSTRA, LH
    MIJLHOFF, FC
    RENES, G
    SPELBOS, A
    JOURNAL OF MOLECULAR STRUCTURE, 1975, 28 (01) : 129 - 135
  • [4] Gas-Phase Conversion of Uranium Mononitride in a Nitrating Atmosphere
    S. A. Kulyukhin
    Yu. M. Nevolin
    A. V. Gordeev
    Radiochemistry, 2019, 61 : 5 - 11
  • [5] Gas-Phase Conversion of Uranium Monocarbide in a Nitrating Atmosphere
    S. A. Kulyukhin
    Yu. M. Nevolin
    A. V. Gordeev
    Radiochemistry, 2019, 61 : 312 - 317
  • [6] Ultrafast internal conversion and photochromism in gas-phase salicylideneaniline
    Silfies, Myles C.
    Mehmood, Arshad
    Kowzan, Grzegorz
    Hohenstein, Edward G.
    Levine, Benjamin G.
    Allison, Thomas K.
    JOURNAL OF CHEMICAL PHYSICS, 2023, 159 (10):
  • [7] Gas-Phase Conversion of Uranium Mononitride in a Nitrating Atmosphere
    Kulyukhin, S. A.
    Nevolin, Yu. M.
    Gordeev, A. V.
    RADIOCHEMISTRY, 2019, 61 (01) : 5 - 11
  • [8] Gas-Phase Conversion of Uranium Monocarbide in a Nitrating Atmosphere
    Kulyukhin, S. A.
    Nevolin, Yu. M.
    Gordeev, A. V.
    RADIOCHEMISTRY, 2019, 61 (03) : 312 - 317
  • [9] Efficient gas-phase VUV frequency up-conversion
    Merriam, Andrew J.
    Sharpe, Scott J.
    Xia, Hui
    Manuszak, Danielle A.
    Yin, G.Y.
    Harris, Stephen E.
    IEEE Journal on Selected Topics in Quantum Electronics, 5 (06): : 1502 - 1509
  • [10] Gas-Phase Fructose Conversion to Furfural in a Microfluidized Bed Reactor
    Carnevali, Davide
    Guevremont, Olivier
    Rigamonti, Marco G.
    Stucchi, Marta
    Cavani, Fabrizio
    Patience, Gregory S.
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (04): : 5580 - 5587
12345