Morphological Study of Two-Phase Polymer Blends During Compounding in a Novel Compounder on the Basis of Elongational Flows

被引：29
作者：
Bouquey, Michel [1 ]
Loux, Cyril [1 ]
Muller, Rene [1 ]
Bouchet, Gilles [2 ]
机构：
[1] Univ Strasbourg, Ecole Europeenne Chim Polymeres & Mat, Equipe Accueil Conventionnee 4379, Lab Ingn Polymeres Hautes Technol, F-67000 Strasbourg, France
[2] Univ Strasbourg, CNRS, Inst Mecan Fluides & Solides, F-67000 Strasbourg, France
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2011年 / 119卷 / 01期
关键词：
computer modeling; mixing; particle size distribution; polymer blends; processing; RHEOLOGICAL PROPERTIES; DROP DEFORMATION; VISCOSITY RATIO; VISCOELASTIC FLUIDS; INTERFACIAL-TENSION; MOLTEN POLYMERS; DISPERSION; SYSTEMS; MIXER; BEHAVIOR;
D O I：
10.1002/app.32645
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new laboratory-scale mixing device based on an original concept was built and tested. This device has important technical features such as tightness to liquids and gases, the possibility of direct specimen molding after mixing, and easy handling of reactive systems. In comparison with existing laboratory mixers, the flow in this mixer is characterized by a high contribution from elongational flow. Morphological data on model polystyrene/poly(methyl methacrylate) blend systems have proved the high distributive and dispersive mixing efficiency in comparison with a classical rotational batch mixer. The influence of different experimental parameters such as the flow rate, mixing time, mixing element geometry, and viscosity ratio of blends is characterized and discussed. Much finer dispersions have been obtained with this new device versus those obtained with a conventional mixer with equivalent specific energy input. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 119: 482-490, 2011
引用
收藏
页码：482 / 490
页数：9
相关论文
共 45 条
[1]  
ABLAZOVA TI, 1975, J APPL POLYM SCI, V19, P1799
[2]   Quantitative analysis of mixer-type rheometers using the Couette analogy [J].
Aït-Kadi, A ;
Marchal, P ;
Choplin, L ;
Chrissemant, AS ;
Bousmina, M .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2002, 80 (06) :1166-1174
[3]   CONSTITUTIVE-EQUATIONS FOR POLYMERIC LIQUIDS [J].
BIRD, RB ;
WIEST, JM .
ANNUAL REVIEW OF FLUID MECHANICS, 1995, 27 :169-193
[4]   Determination of shear rate and viscosity from batch mixer data [J].
Bousmina, M ;
Ait-Kadi, A ;
Faisant, JB .
JOURNAL OF RHEOLOGY, 1999, 43 (02) :415-433
[5]   Temperature dependence of the interfacial tension of PS/PMMA, PS/PE, and PMMA/PE blends [J].
Carriere, CJ ;
Biresaw, G ;
Sammler, RL .
RHEOLOGICA ACTA, 2000, 39 (05) :476-482
[6]   Analysis of polymer blend morphologies from transmission electron micrographs [J].
Corté, L ;
Leibler, L .
POLYMER, 2005, 46 (17) :6360-6368
[7]   Drop deformation during elongational flow in blends of viscoelastic fluids. Small deformation theory and comparison with experimental results [J].
Delaby, I ;
Ernst, B ;
Muller, R .
RHEOLOGICA ACTA, 1995, 34 (06) :525-533
[8]   DROPLET DEFORMATION IN POLYMER BLENDS DURING UNIAXIAL ELONGATIONAL FLOW - INFLUENCE OF VISCOSITY RATIO FOR LARGE CAPILLARY NUMBERS [J].
DELABY, I ;
ERNST, B ;
GERMAIN, Y ;
MULLER, R .
JOURNAL OF RHEOLOGY, 1994, 38 (06) :1705-1720
[9]   Drop deformation in polymer blends during elongational flow [J].
Delaby, I ;
Ernst, B ;
Muller, R .
JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1996, B35 (3-4) :547-561
[10]   A STUDY ON POLYMER BLENDING MICRORHEOLOGY .4. THE INFLUENCE OF COALESCENCE ON BLEND MORPHOLOGY ORIGINATION [J].
ELMENDORP, JJ ;
VANDERVEGT, AK .
POLYMER ENGINEERING AND SCIENCE, 1986, 26 (19) :1332-1338
12345