Iridium-catalyzed asymmetric allylic substitution with aryl zinc reagents

被引:71
作者
Alexakis, Alexandre [1 ]
El Hajjaji, Samir [1 ]
Polet, Damien [1 ]
Rathgeb, Xavier [1 ]
机构
[1] Univ Geneva, Dept Chim Organ, CH-1211 Geneva 4, Switzerland
关键词
D O I
10.1021/ol0713842
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Thanks to iridium catalysis, arylzinc reagents undergo regioselective allylic substitution with very high enantioselectivity, when associated with phosphoramidite ligands.
引用
收藏
页码:3393 / 3395
页数:3
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