β-Y(BO2)3 - a new member of the β-Ln(BO2)3 (Ln = Nd, Sm, Gd-Lu) structure family

被引：7

作者：

Schmitt, Martin K. ^{[1
]}

Huppertz, Hubert ^{[1
]}

机构：

[1] Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2017年 / 72卷 / 12期

关键词：

crystal structure; high-pressure chemistry; vibrational spectroscopy; yttrium borate; BOND-VALENCE PARAMETERS; CRYSTAL-STRUCTURE; PRESSURE; CHEMISTRY;

D O I：

10.1515/znb-2017-0151

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

beta-Y(BO2)(3) was synthesized in a Walker-type multianvil module at 5.9 GPa/1000 degrees C. The crystal structure has been elucidated through single-crystal X-ray diffraction. beta-Y( BO2)(3) crystallizes in the orthorhombic space group Pnma (no. 62) with the lattice parameters a = 15.886(2), b = 7.3860(6), and c = 12.2119(9) angstrom. Its crystal structure will be discussed in the context of the isotypic lanthanide borates beta-Ln(BO2)(3) (Ln = Nd, Sm, Gd-Lu).

引用

页码：983 / 988

页数：6

共 21 条

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