Synthesis of Lignin-Derived Bisphenols Catalyzed by Lignosulfonic Acid in Water for Polycarbonate Synthesis

被引：40

作者：

Chen, Qin ^{[1
,2
]}

Huang, Wei ^{[3
]}

Chen, Peng ^{[3
]}

Peng, Chang ^{[1
]}

Xie, Haibo ^{[1
]}

Zhao, Zongbao Kent ^{[1
]}

Sohail, Muhammad ^{[1
]}

Bao, Ming ^{[2
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian, Peoples R China

[2] Dalian Univ Technol, Dalian 116023, Peoples R China

[3] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo Key Lab Polymer Mat, Ningbo 315201, Zhejiang, Peoples R China

来源：

CHEMCATCHEM | 2015年 / 7卷 / 07期

关键词：

biomass; green chemistry; lignin-derived bisphenol; sustainable chemistry; water chemistry; RENEWABLE BISPHENOLS; DIPHENOLIC ACID; VANILLIN; POLYMERS; HYDROGENOLYSIS; CONVERSION; CHEMISTRY; MEMBRANES; MONOMER; RESIN;

D O I：

10.1002/cctc.201500010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lignosulfonic acid, a byproduct of the paper industry, was demonstrated to be an efficient and green catalyst in water for the stoichiometric condensation of creosol with formaldehyde to synthesize lignin-derived renewable bisphenols. The distribution and structures of the products were confirmed by (HNMR)-H-1, (CNMR)-C-13, and FTIR spectroscopy and X-ray analysis; furthermore, a possible reaction mechanism was proposed. A polycarbonate was prepared from the bisphenol product and characterized as a model application, and thermogravimetric analysis (TGA) showed that decomposition occurred in a single stage with the maximum rate of degradation at approximately 420 degrees C. Differential scanning calorimetry (DSC) analysis showed that the glass transition temperature and melting peak of the polycarbonate were approximately 122 and 314 degrees C, respectively. The environmentally friendly characteristics of this study are featured by the integrated utilization of a biorenewable feedstock, a green biomacromolecule catalyst, and a green solvent for the preparation of valuable biochemicals and materials.

引用

页码：1083 / 1089

页数：7

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