Effect of intermediate layer on gas separation performance of disk supported carbon membrane

被引:15
作者
Ismail, N. H. [1 ,2 ]
Salleh, W. N. W. [1 ,2 ]
Sazali, N. [1 ,2 ]
Ismail, A. F. [1 ,2 ]
机构
[1] Univ Teknol Malaysia, Adv Membrane Technol Res Ctr AMTEC, Skudai 81310, Johor Darul Tak, Malaysia
[2] Univ Teknol Malaysia, Fac Chem & Energy Engn FCEE, Skudai, Johor Darul Tak, Malaysia
关键词
Carbon dioxide; co-polyimide P-84; gas separation; spray coating; supported carbon membrane; MOLECULAR-SIEVE MEMBRANES; HOLLOW-FIBER MEMBRANES; CHEMICAL-MODIFICATION; COMPOSITE MEMBRANES; FABRICATION; CO2; SUBSTRATE; VARIABLES; MIXTURES; CO2/CH4;
D O I
10.1080/01496395.2017.1321671
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Porous alumina disk ceramic was decorated with various types of intermediate layers via one-step spray coating-carbonization technique. P-84 (BTDA-TDI/MDI) polymeric solution was sprayed on the alumina disk with an incorporation of intermediate layer. The membrane was carbonized at 700 degrees C under nitrogen (N-2) atmosphere with a heating rate of 3 degrees C/min. The resultant carbon membrane was characterized in terms of its thermal stability, structural morphology, and gas permeation properties. A high-performance carbon membrane was obtained with the intermediate layer of the alumina powder, which exhibited the best selectivity of O-2/N-2, CO2/N-2 and CO2/CH4 of 4.39, 19.89 and 58.43, respectively.
引用
收藏
页码:2137 / 2149
页数:13
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