Mesoporous ZSM-5 Zeolite-Supported Ru Nanoparticles as Highly Efficient Catalysts for Upgrading Phenolic Biomolecules

被引：151
作者：
Wang, Liang [1 ]
Zhang, Jian [1 ]
Yi, Xianfeng [2 ]
Zheng, Anmin [2 ]
Deng, Feng [2 ]
Chen, Chunyu [1 ]
Ji, Yanyan [1 ]
Liu, Fujian [1 ]
Meng, Xiangju [1 ]
Xiao, Feng-Shou [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Peoples R China
[2] Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Natl Ctr Magnet Resonance Wuhan, Wuhan 430071, Peoples R China
来源：
ACS CATALYSIS | 2015年 / 5卷 / 05期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
phenolic biomolecules; hydrodeoxygenation; mesoporous zeolite; Ru catalyst; biomass conversion; BIO-OIL; CRYSTALLINE ZEOLITE; RANGE ALKANES; FORMIC-ACID; P-31; NMR; CONVERSION; HYDRODEOXYGENATION; BIOMASS; FUELS; HYDRODESULFURIZATION;
D O I：
10.1021/acscatal.5b00083
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Zeolite-based catalysts have been widely used in the conversion of biomass recently, but the catalytic yields of the desired products are strongly limited by the relatively small micropores of zeolite. Here, we reported a hierarchically porous ZSM-5 zeolite with micropore and b-axis-aligned mesopore-supported Ru nanoparticles (Ru/HZSM-5-OM) that are highly efficient for the hydrodeoxygenation of both small and bulky phenolic biomolecules to the corresponding alkanes. Compared with the conventional ZSM-5 zeolite-supported Ru catalyst, the high catalytic activities and alkane selectivities over Ru/HZSM-5-OM are attributed to the abundant exposed acidic sites in HZSM-5-OM with open mesopores. This feature is potentially important for future phenolic bio-oil upgrading.
引用
收藏
页码：2727 / 2734
页数：8
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共 51 条
  • [1] Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions
    Bi, Qng-Yuan
    Du, Xian-Long
    Liu, Yong-Mei
    Cao, Yong
    He, He-Yong
    Fan, Kang-Nian
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (21) : 8926 - 8933
  • [2] Amphiphilic organosilane-directed synthesis of crystalline zeolite with tunable mesoporosity
    Choi, Minkee
    Cho, Hae Sung
    Srivastava, Rajendra
    Venkatesan, Chithravel
    Choi, Dae-Heung
    Ryoo, Ryong
    [J]. NATURE MATERIALS, 2006, 5 (09) : 718 - 723
  • [3] Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts
    Choi, Minkee
    Na, Kyungsu
    Kim, Jeongnam
    Sakamoto, Yasuhiro
    Terasaki, Osamu
    Ryoo, Ryong
    [J]. NATURE, 2009, 461 (7261) : 246 - U120
  • [4] Xylose Isomerization to Xylulose and its Dehydration to Furfural in Aqueous Media
    Choudhary, Vinit
    Pinar, Ana B.
    Sandler, Stanley I.
    Vlachos, Dionisios G.
    Lobo, Raul F.
    [J]. ACS CATALYSIS, 2011, 1 (12): : 1724 - 1728
  • [5] Chemical routes for the transformation of biomass into chemicals
    Corma, Avelino
    Iborra, Sara
    Velty, Alexandra
    [J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2411 - 2502
  • [6] Elucidation of Diels-Alder Reaction Network of 2,5-Dimethylfuran and Ethylene on HY Zeolite Catalyst
    Do, Phuong T. M.
    McAtee, Jesse R.
    Watson, Donald A.
    Lobo, Raul F.
    [J]. ACS CATALYSIS, 2013, 3 (01): : 41 - 46
  • [7] Synergy effect in the HDO of phenol over Ni-W catalysts supported on active carbon: Effect of tungsten precursors
    Echeandia, S.
    Arias, P. L.
    Barrio, V. L.
    Pawelec, B.
    Fierro, J. L. G.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 101 (1-2) : 1 - 12
  • [8] Extraordinarily High Activity in the Hydrodesulfurization of 4,6-Dimethyldibenzothiophene over Pd Supported on Mesoporous Zeolite Y
    Fu, Wenqian
    Zhang, Lei
    Tang, Tiandi
    Ke, Qingping
    Wang, Shun
    Hu, Jianbo
    Fang, Guoyong
    Li, Jixue
    Xiao, Feng-Shou
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (39) : 15346 - 15349
  • [9] Impact of solvent for individual steps of phenol hydrodeoxygenation with Pd/C and HZSM-5 as catalysts
    He, Jiayue
    Zhao, Chen
    Lercher, Johannes A.
    [J]. JOURNAL OF CATALYSIS, 2014, 309 : 362 - 375
  • [10] Hydrodeoxygenation and coupling of aqueous phenolics over bifunctional zeolite-supported metal catalysts
    Hong, Do-Young
    Miller, Stephen J.
    Agrawal, Pradeep K.
    Jones, Christopher W.
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (07) : 1038 - 1040
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