Study of the thermal decomposition on Pt(II) complexes with cycloalkanespiro-5'-hydantoins

被引：6

作者：

Bakalova, A. ^{[1
]}

Ivanov, D. ^{[1
]}

机构：

[1] Med Univ, Fac Pharm, Dept Chem, BU-1000 Sofia, Bulgaria

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2007年 / 89卷 / 01期

关键词：

Pt(II) complexes; spirohydantoins; thermal analysis;

D O I：

10.1007/s10973-005-7474-1

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The thermal decomposition of the Pt(II) complexes with cyclobutane-and cycloheptanespiro-5'-hydantoins were studied by TG and DTA techniques. The Pt(II) complex with cyclobutanespiro-5'hydantoin (PtCBH) was stable up to 115 degrees C (388 K) and Pt(II) complex with cycloheptanespiro-5'-hydantoin (PtCHTH) was stable up to 150 degrees C (423 K). After the thermal decomposition of PtCBH the solid residue was platinum, while the decomposition of PtCHTH gave a mixture of platinum carbides (PtC2, Pt2C3).

引用

页码：257 / 260

页数：4