Solvatochromism of BODIPY-Schiff Dye

被引：39

作者：

Filarowski, Aleksander ^{[1
,4
]}

Lopatkova, Marina ^{[1
]}

Lipkowski, Pawel ^{[2
]}

Van der Auweraer, Mark ^{[3
]}

Leen, Volker ^{[3
]}

Dehaen, Wim ^{[3
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

[2] Wroclaw Univ Technol, Inst Phys & Theoret Chem, Theoret Chem Grp, PL-50370 Wroclaw, Poland

[3] Katholieke Univ Leuven, Dept Chem, B-3001 Leuven, Belgium

[4] Tyumen State Univ Architecture & Civil Engn, Tyumen 625001, Russia

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2015年 / 119卷 / 06期

关键词：

NEAR-INFRARED NIR; OPTICAL SIGNATURES; BASIS-SETS; APPROXIMATION; FLUORESCENCE; STATES; TIME; SOLVENT; ANION;

D O I：

10.1021/jp508718d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A borondipyrrin chromophore connected with an o-hydroxyaryl aldimine by a diazo bridge (BODIPY-Schiff dye) has been developed. The photophysical properties of the BODIPY-Schiff dye have been investigated with UV, steady-state, and time-resolved fluorimetry. The spectral features have been characterized with respect to density functional theory and time-dependent density functional theory. The conformational analysis of the studied compound has been accomplished both in the ground and excited states. A scheme of the processes occurring in the BODIPY-Schiff dye has been proposed.

引用

页码：2576 / 2584

页数：9

共 62 条

[1] Toward reliable density functional methods without adjustable parameters: The PBE0 model [J].

Adamo, C ;

Barone, V .

JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (13) :6158-6170

[2] Energy- and charge-transfer processes in a perylene-BODIPY-pyridine tripartite array [J].

Alamiry, Mohammed A. H. ;

Harriman, Anthony ;

Mallon, Laura J. ;

Ulrich, Gilles ;

Ziessel, Raymond .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (16) :2774-2782

[3] Smart molecules at work-mimicking advanced logic operations [J].

Andreasson, Joakim ;

Pischel, Uwe .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :174-188

[4]

Antonov L., 2014, TAUTOMERISM METHODS

[5] Solvent and pH dependent fluorescent properties of a dimethylaminostyryl borondipyrromethene dye in solution [J].

Baruah, Mukulesh ;

Qin, Wenwu ;

Flors, Cristina ;

Hofkens, Johan ;

Valle, Renaud A. L. ;

Beljonne, David ;

Van der Auweraer, Mark ;

De Borggraeve, Wim M. ;

Boens, Noel .

JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (18) :5998-6009

[6] Treatment of electronic excitations within the adiabatic approximation of time dependent density functional theory [J].

Bauernschmitt, R ;

Ahlrichs, R .

CHEMICAL PHYSICS LETTERS, 1996, 256 (4-5) :454-464

[7] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[8] 4,4′-Difluoro-4-bora-3a,4a-diaza-s-indacenes (BODIPYs) as components of novel light active materials [J].

Benstead, Michael ;

Mehl, Georg H. ;

Boyle, Ross W. .

TETRAHEDRON, 2011, 67 (20) :3573-3601

[9] Fluorescence lifetime standards for time and frequency domain fluorescence spectroscopy [J].

Boens, Noel ;

Qin, Wenwu ;

Basaric, Nikola ;

Hofkens, Johan ;

Ameloot, Marcel ;

Pouget, Jacques ;

Lefevre, Jean-Pierre ;

Valeur, Bernard ;

Gratton, Enrico ;

vandeVen, Martin ;

Silva, Norberto D., Jr. ;

Engelborghs, Yves ;

Willaert, Katrien ;

Sillen, Alain ;

Rumbles, Garry ;

Phillips, David ;

Visser, Antonie J. W. G. ;

van Hoek, Arie ;

Lakowicz, Joseph R. ;

Malak, Henryk ;

Gryczynski, Ignacy ;

Szabo, Arthur G. ;

Krajcarski, Don T. ;

Tamai, Naoto ;

Miura, Atsushi .

ANALYTICAL CHEMISTRY, 2007, 79 (05) :2137-2149

[10] Fluorescent indicators based on BODIPY [J].

Boens, Noel ;

Leen, Volker ;

Dehaen, Wim .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (03) :1130-1172

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