A regenerative chemodosimeter based on metal-induced dye formation for the highly selective and sensitive optical determination of Hg2+ ions

被引:347
作者
Ros-Lis, JV
Marcos, MD
Mártinez-Máñez, R
Rurack, K
Soto, J
机构
[1] Univ Politecn Valencia, Dept Quim, Ctr Invest Quim Mol Aplicada, Valencia 46071, Spain
[2] BAM, D-12489 Berlin, Germany
关键词
chemodosimeter; dyes; fluorometric analysis; mercury; spectrophotometric analysis;
D O I
10.1002/anie.200500583
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Into the blue: Hg2+-ion-triggered formation of a brightly fluorescent squaraine dye is used as a novel approach for the design of highly selective and sensitive chromofluorogenic probes for the analysis of Hg2+ ions down to concentrations below 2 ppb (see picture). Through the adsorption of the sensor on a solid support a prototype reusable test strip is also generated. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4405 / 4407
页数:3
相关论文
共 33 条
  • [11] Cyclic and open-chain aza-oxa ferrocene-functionalised derivatives as receptors for the selective electrochemical sensing of toxic heavy metal ions in aqueous environments
    Lloris, JM
    Martínez-Máñez, R
    Padilla-Tosta, ME
    Pardo, T
    Soto, J
    Beer, PD
    Cadman, J
    Smith, DK
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (14): : 2359 - 2369
  • [12] Selective electrochemical recognition of mercury in water by a redox-functionalised aza-oxa crown derivative
    Lloris, JM
    Martínez-Máñez, R
    Pardo, T
    Soto, J
    Padilla-Tosta, ME
    [J]. CHEMICAL COMMUNICATIONS, 1998, (07) : 837 - 838
  • [13] Magos L, 1997, MET IONS BIOL SYST, V34, P321
  • [14] Chromo- and fluororeactands: Indicators for detection of neutral analytes by using reversible covalent-bond chemistry
    Mohr, GJ
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (05) : 1082 - 1090
  • [15] New Hg2+-selective chromo- and fluoroionophore based upon 8-hydroxyquinoline
    Moon, SY
    Cha, NR
    Kim, YH
    Chang, SK
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (01) : 181 - 183
  • [16] Fluorescence-based sensor membrane for mercury(II) detection
    Murkovic, I
    Wolfbeis, OS
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 1997, 39 (1-3) : 246 - 251
  • [17] A "Turn-On" fluorescent sensor for the selective detection of mercuric ion in aqueous media
    Nolan, EM
    Lippard, SJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (47) : 14270 - 14271
  • [18] Heterogeneous colorimetric sensor for mercuric salts
    Palomares, E
    Vilar, R
    Durrant, JR
    [J]. CHEMICAL COMMUNICATIONS, 2004, (04) : 362 - 363
  • [19] A fluorescent probe for the detection of NAD(P)H
    Roeschlaub, CA
    Maidwell, NL
    Rezai, MR
    Sammes, PG
    [J]. CHEMICAL COMMUNICATIONS, 1999, (17) : 1637 - 1638
  • [20] Highly selective chromogenic signaling of Hg2+ in aqueous media at nanomolar levels employing a squaraine-based reporter
    Ros-Lis, JV
    Martínez-Máñez, R
    Rurack, K
    Sancenón, F
    Soto, J
    Spieles, M
    [J]. INORGANIC CHEMISTRY, 2004, 43 (17) : 5183 - 5185