Direct synthesis of H2O2 catalyzed by Pd nanoparticles encapsulated in the multi-layered polyelectrolyte nanoreactors on a charged sphere

被引：21

作者：

Chung, Young-Min ^{[1
]}

Kwon, Yong-Tak ^{[1
]}

Kim, Tae Jin ^{[1
]}

Oh, Seung-Hoon ^{[1
]}

Lee, Chang-Soo ^{[2
]}

机构：

[1] SK Innovat, Global Technol, Catalyst & Proc R&D Ctr, Catalyst Lab, Taejon 305712, South Korea

[2] Chungnam Natl Univ, Dept Chem Engn, Taejon 305764, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 20期

关键词：

HYDROGEN-PEROXIDE; PALLADIUM NANOPARTICLES; SELECTIVE HYDROGENATION; FILMS; RESINS; OXYGEN;

D O I：

10.1039/c1cc11180a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient and industrially viable catalyst design for the direct synthesis of H2O2 from H-2 and O-2 was realized by the encapsulation of Pd nanoparticles in polyelectrolyte multi-layers on a sulfonated resin. The continuous production of 9.9 wt% H2O2 was achieved under intrinsically safe and non-corrosive conditions without any loss of activity.

引用

页码：5705 / 5707

页数：3

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