Solvothermal synthesis and crystal structure of a novel inorganic-organic hybrid material, Fe2O(OH) (C5H4NCOO) SO4

被引：0

作者：

Guo, HY ^{[1
]}

Li, ZH

Li, XY

Zhang, CY

Wang, RJ

机构：

[1] Beijing Univ Chem Technol, Dept Chem, Beijing 100029, Peoples R China

[2] Tsinghua Univ, Dept Chem, Beijing 100083, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2003年 / 21卷 / 04期

关键词：

inorganic-organic hybrid material; ferric isonicotinate-sulphate; solvothermal synthesis; crystal structure;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel inorganic-organic hybrid material, Fe2O(OH)(C5H4-NCOO)SO4 was synthesized via solvothermal route using a reaction of FeCl3.6H(2)O, KCNS, and 4-cyanopyridine in aqueous solution of H2O2 and ethanol at 130 degreesC for 3 d. The compound crystallized in monoclinic space group P2(1), with cell parameters a = 0.73850(15) nm, b = 0.65100 (13) nm, c = 1.0546 (2) nm, beta = 90.36 (3)degrees, V = 0.50700(18) nm(3) and Z = 2. The structure is constructed with inorganic layered [Fe2O (OH) SO4](+) cations linked by organic (C5H4NCOO)(-) anions. The compound is thermally stable up to approximately 240 degreesC.

引用

页码：466 / 470

页数：5

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