A novel rearrangement of N-Propargyl vinylaziridines. Mechanistic diversity in the aza-[2,3]-Wittig rearrangement

被引：22

作者：

Ahman, J ^{[1
]}

Somfai, P ^{[1
]}

机构：

[1] LUND UNIV,INST TECHNOL,CTR CHEM & CHEM ENGN,S-22100 LUND,SWEDEN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 14期

关键词：

D O I：

10.1016/0040-4039(96)00302-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Propargyl vinylaziridines 4a-c have been prepared. The anionic rearrangement of 4a,b gives the trans-2,6-disubstituted tetrahydropyridines 5a,b, respectively, as the major products while 4c gives 1-pyrroline 7c exlusively. The mechanism for the formation of pyrrolines in these reactions is discussed. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：2495 / 2498

页数：4

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