Total hydrogenation of furan derivatives over silica-supported Ni-Pd alloy catalyst

被引：205
作者：
Nakagawa, Yoshinao [1 ]
Tomishige, Keiichi [1 ]
机构：
[1] Tohoku Univ, Dept Appl Chem, Sch Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源：
CATALYSIS COMMUNICATIONS | 2010年 / 12卷 / 03期
关键词：
Hydrogenation; Biomass; Furan derivatives; Nickel; Palladium; X-RAY-DIFFRACTION; ORGANOMETALLIC CHEMISTRY; SURFACE CHARACTERIZATION; BIOMASS; FUELS; HYDROGENOLYSIS; HYDROCARBONS; COEXCHANGE; REACTIVITY; CELLULOSE;
D O I：
10.1016/j.catcom.2010.09.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Ni-Pd bimetallic catalysts supported on silica were prepared by co-impregnation method The catalyst with Ni/Pd = 7 showed the best catalytic performance for the hydrogenation of 5 hydroxymethyl-2-furaldehyde (HMF) The catalyst was more active than commercial Raney Ni and more selective than Pd/C The yield of 2 5-bis ( hydroxymethyl)tetrahydrofuran reached 96% Hydrogenation of other furanic compounds cyclohexanone phenol and alkenols also proceeded Characterizations by TEM and XRD revealed that Ni-Pd alloy particles were formed on Ni-Pd/SiO2 (Ni/Pd = 7) (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码：154 / 156
页数：3
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