A Fundamental Study on Carbon Composites of FeF3•0.33H2O as Open-framework Cathode Materials for Calcium-ion Batteries

被引:12
|
作者
Murata, Yoshiaki [1 ]
Minami, Ryoji [1 ]
Takada, Shoki [1 ]
Aoyanagi, Kengo [1 ]
Tojo, Tomohiro [1 ]
Inada, Ryoji [1 ]
Sakurai, Yoji [1 ]
机构
[1] Toyohashi Univ Technol, Dept Elect & Elect Informat Engn, Tempaku Ku, 1-1 Hibarigaoka, Toyohashi, Aichi 4418580, Japan
来源
IRAGO CONFERENCE 2016: 360 DEGREE OUTLOOK ON CRITICAL SCIENTIFIC AND TECHNOLOGICAL CHALLENGES FOR A SUSTAINABLE SOCIETY | 2017年 / 1807卷
关键词
ELECTROCHEMICAL PERFORMANCE; LITHIUM;
D O I
10.1063/1.4974787
中图分类号
TP3 [计算技术、计算机技术];
学科分类号
0812 ;
摘要
Carbon composites of open-framework iron fluoride (FeF3 center dot 0.33H(2)O/C) was investigated as a new cathode material for calcium ion batteries for the first time. FeF3 center dot 0.33H(2)O/C delivers a relatively large capacity of ca. 110mAhg(-1). Its reversible capacity was greatly improved over non-composite FeF3 center dot 0.33H(2)O. During the first discharge and discharge-charge, insertion/extraction of Ca2+ into/from FeF3 center dot 0.33H(2)O/C were confirmed by an ex-situ X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy (EDX) analysis. From the ex-situ analysis results, it was confirmed that Ca2+ was inserted and extracted with redox of Fe.
引用
收藏
页数:8
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