Synthesis and properties of spiroxazine polymer derived from cyclopolymerization of diallyldimethylammonium chloride and diallylamine

被引：13

作者：

Kim, SH ^{[1
]}

Park, SY

Yoon, NS

Keum, SR

Koh, K

机构：

[1] Kyungpook Natl Univ, Dept Dyeing & Finishing, Taegu 702701, South Korea

[2] Korea Univ, Dept New Mat Chem, Choongnam 339700, South Korea

[3] Pusan Natl Univ, Coll Pharm, Pusan 609735, South Korea

来源：

DYES AND PIGMENTS | 2005年 / 66卷 / 02期

关键词：

cyclopolymerization; spiroxazine; cyanuric chloride; first-order kinetics; photoviscosity effect;

D O I：

10.1016/j.dyepig.2004.08.014

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Cyclopolyinerization of diallyldimethylammonium chloride and diallylamine containing photochromic spiroxazine was carried out by free radical initiation. The resulting polymer was found to be photochromic in solution and thin solid film. The viscosity of a methanol solution of the polymer was reversively reduced by as much as 5% upon UV irradiation, the initial value being restored in the dark. (c) 2004 Published by Elsevier Ltd.

引用

页码：155 / 160

页数：6

共 14 条

[1] PREPARATION AND POLYMERIZATION OF UNSATURATED QUATERNARY AMMONIUM COMPOUNDS .8. A PROPOSED ALTERNATING INTRAMOLECULAR-INTERMOLECULAR CHAIN PROPAGATION [J].

BUTLER, GB ;

ANGELO, RJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (12) :3128-3131

[2] THE FORMATION OF LINEAR POLYMERS FROM DIENE MONOMERS BY A CYCLIC POLYMERIZATION MECHANISM .1. THE STRUCTURE OF POLY-(DIALLYLAMMONIUM HALIDES) [J].

BUTLER, GB ;

CRAWSHAW, A ;

MILLER, WL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (14) :3615-3618

[3]

BUTLER GB, 1951, J AM CHEM SOC, V73, P894

[4]

BUTLER GB, 1960, Patent No. 2926161

[5]

DURR H, 1990, PHTOCHROMISM MOL SYS

[6] PHOTORESPONSIVE POLYMERS .2. REVERSIBLE SOLUTION VISCOSITY CHANGE OF POLYAMIDES HAVING AZOBENZENE RESIDUES IN THE MAIN CHAIN [J].

IRIE, M ;

HIRANO, Y ;

HASHIMOTO, S ;

HAYASHI, K .

MACROMOLECULES, 1981, 14 (02) :262-267

[7] PHOTORESPONSIVE POLYMERS - REVERSIBLE SOLUTION VISCOSITY CHANGE OF POLY(METHYL METHACRYLATE) HAVING SPIROBENZOPYRAN SIDE GROUPS [J].

IRIE, M ;

MENJU, A ;

HAYASHI, K .

MACROMOLECULES, 1979, 12 (06) :1176-1180

[8] A NEW PHOTOCHROMIC SPIRO[3H-1,4-OXAZINE] [J].

KAWAUCHI, S ;

YOSHIDA, H ;

YAMASHINA, N ;

OHIRA, M ;

SAEDA, S ;

IRIE, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (01) :267-268

[9] Surface plasmon resonance spectroscopy on the interaction of a self-assembled monolayer with linear hydrocarbon such as pentane, hexane, heptane and octane [J].

Kim, SH ;

Choi, SW ;

Suh, HJ ;

Jin, SH ;

Gal, YS ;

Koh, K .

DYES AND PIGMENTS, 2002, 55 (01) :17-25

[10] PHOTOVISCOSITY EFFECT [J].

LOVRIEN, R .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1967, 57 (02) :236-&

← 1 2 →