Ultra-low friction, superhydrophobic, plasma micro-nanotextured fluorinated ethylene propylene (FEP) surfaces

Fluorine-containing polymers have attracted a lot of interest due to their hydrophobic nature, which enables a number of functionalities such as low friction, self-cleaning, anti-sticking, etc. Fluorinated ethylene propylene (FEP) is a copolymer of hexafluoropropylene and tetrafluoroethylene. In contrast to polytetrafluoroethylene (PTFE), FEP is melt-processable using injection molding and it is highly transparent and resistant to sunlight. Here, we transform fluorinated ethylene propylene (FEP) surfaces to superhydrophobic using plasma processing (i.e. plasma etching with simultaneous micro-nanotexturing followed by plasma deposition). Two different plasma reactors (an inductively coupled reactor and a reactive ion etcher) and different etching conditions are used in order to micro-nanotexture FEP surfaces. Superhydrophobicity is achieved after plasma deposition of a thin (30 nm) fluorocarbon coating. Subsequently, we probe their frictional properties against water drops using a tilting stage. In particular, we demonstrate wetting control of FEP surfaces with water static water contact angle ranging from 95 degrees to 168 degrees and hysteresis down to 1-2 degrees. Video analysis of drops moving on different FEP surfaces shows that water drops exhibit reduced friction as etching time increases so that a hierarchical morphology is created. This is achieved using both plasma reactors, whereas the optimum performance is observed for the 10 min etched surface in a inductively coupled plasma reactor in which friction force becomes 0.7-1 mu N, which corresponds to an ultra-low dynamic coefficient of friction (at least one order of magnitude lower to that of untreated FEP).