In tandem or alone: a remarkably selective transfer hydrogenation of alkenes catalyzed by ruthenium olefin metathesis catalysts

被引：23
|
作者：
Zielinski, Grzegorz Krzysztof [1 ]
Samojlowicz, Cezary [1 ]
Wdowik, Tomasz [1 ]
Grela, Karol [1 ]
机构：
[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 09期
关键词：
NHC=N-HETEROCYCLIC CARBENE; FORMIC-ACID; CROSS-METATHESIS; TRANSFER-HYDROGENOLYSIS; AMBIENT-TEMPERATURE; MECHANISTIC ASPECTS; COMPLEXES; ALCOHOLS; DEHYDROGENATION; ISOMERIZATION;
D O I：
10.1039/c4ob02480j
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A system for transfer hydrogenation of alkenes, composed of a ruthenium metathesis catalyst and HCOOH, is presented. This operationally simple system can be formed directly after a metathesis reaction to effect hydrogenation of the metathesis product in a single-pot. These hydrogenation conditions are applicable to a wide range of alkenes and offer remarkable selectivity.
引用
收藏
页码：2684 / 2688
页数：5
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