Catalytic Reductive Vinylidene Transfer Reactions

被引：53
作者：
Pal, Sudipta [1 ]
Zhou, You-Yun [1 ]
Uyeda, Christopher [1 ]
机构：
[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2017年 / 139卷 / 34期
基金：
美国国家科学基金会;
关键词：
BUTTENBERG-WIECHELL REARRANGEMENT; DINUCLEAR NICKEL-COMPLEXES; ALKYLIDENECYCLOPROPANE DERIVATIVES; UNSATURATED CARBENES; METAL VINYLIDENES; ORGANIC-SYNTHESIS; TERMINAL ALKYNES; CHEMISTRY; ALKYLIDENECARBENES; METHYLENECYCLOPROPANES;
D O I：
10.1021/jacs.7b05901
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Methylenecyclopropanes are important synthetic intermediates that possess strain energies exceeding those of saturated cyclopropanes by >10 kcal/mol. This report describes a catalytic reductive methylenecyclopropanation reaction of simple olefins, utilizing 1,1-dichloroalkenes as vinylidene precursors. The reaction is promoted by a dinuclear Ni catalyst, which is proposed to access Ni-2(vinylidenoid) intermediates via C-Cl oxidative addition.
引用
收藏
页码：11686 / 11689
页数：4
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