An Unprecedented AB2 Tetrahedra Network Structure Type in a High-Pressure Phase of Phosphorus Oxonitride (PON)

被引：20
作者：
Baumann, Dominik [1 ]
Sedlmaier, Stefan J. [1 ]
Schnick, Wolfgang [1 ]
机构：
[1] Univ Munich, Dept Chem, Lehrstuhl Anorgan Festkorperchem, D-81377 Munich, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 19期
关键词：
high-pressure chemistry; nitrides; phosphorus; solid-state structures; structure elucidation; SOLID-STATE CHEMISTRY; CRYSTAL-STRUCTURES; NITRIDE GLASSES; OXYNITRIDE PON; GENERATION; INVARIANTS; TOPOLOGY; 3-RINGS;
D O I：
10.1002/anie.201200811
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Restructuring: An unprecedented framework structure made up of tetrahedra has been discovered in a novel high-pressure polymorph of the phosphorus oxonitride PON by treating a single-source precursor at 12 GPa and 1250°C. It is the first polymorph of PON that does not crystallize in a structure type known from SiO 2. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4707 / 4709
页数：3
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