Crystal structures of Saturn-like C50Cl10 and pineapple-shaped C64Cl4:: Geometric implications of double- and triple-pentagon-fused chlorofullerenes

被引：101

作者：

Han, Xiao

Zhou, Sheng-Jun

Tan, Yuan-Zhi

Wu, Xin

Gao, Fei

Liao, Zhao-Jiang

Huang, Rong-Bin

Feng, Yu-Qi ^{[2
]}

Lu, Xin

Xie, Su-Yuan ^{[1
]}

Zheng, Lan-Sun

机构：

[1] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

[2] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 29期

关键词：

aromaticity; cage compounds; density functional calculations; fullerenes; X-ray diffraction;

D O I：

10.1002/anie.200800338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Planet pineapple: The structures of two isolated pentagon rule (IPR)-violating chlorofullerenes (C50Cl10 and C64Cl4; see picture) are determined by X-ray crystallography and their stabilities rationalized by relief of strain at the active pentagon-fusion carbon atoms whilst maintaining the aromaticity of their carbon skeletons. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5340 / 5343

页数：4

共 44 条

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[Anonymous], 2001, ANGEW CHEM, V113, P809

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