Rhodium(III)-catalyzed internal oxidative coupling of N-hydroxyanilides with alkenes via C-H activation

被引：11

作者：

Wen, Jing ^{[1
]}

Wu, An ^{[2
]}

Chen, Pei ^{[1
]}

Zhu, Jin ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Nanjing 210093, Jiangsu, Peoples R China

[2] Nanjing Univ, Kuang Yaming Honors Sch, Nanjing 210093, Jiangsu, Peoples R China

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 38期

基金：

中国国家自然科学基金;

关键词：

Rhodium; Anilides; Internal oxidation; Alkenes; C-H activation; BOND ACTIVATION; DIRECTING GROUP; ORTHO-ARYLATION; ANILIDES; INDOLES; ARENES; AMIDATION; ALKYNES; FUNCTIONALIZATION; CYCLIZATION;

D O I：

10.1016/j.tetlet.2015.07.070

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Described herein is an efficient new method for ortho-olefination of anilides in the presence of AgSbF6 and NaOAc via rhodium(III)-catalyzed internal oxidative C-H bond activation based on hydroxyl as directing and oxidative group. A range of alkenes and functional groups on acetanilides is supported and a possible mechanism is proposed according to the experimental results. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：5282 / 5286

页数：5

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