NIR-OLED structures based on lanthanide coordination compounds: synthesis and luminescent properties

Electroluminescence complexes based on ytterbium and 5-methyl-2-phenyl-4-(2,2,2- trifluoroacetyl)-2,4-dihydro-3H-pyrazol-3-one (HL) ligand and various diimine-type ancillary ligands (2,2-bipyridine, bathophenanthroline, 1,10-phenanthroline) have been synthesized, and corresponding crystals were investigated. [Yb(L)(3)(bipy)] and [Yb(L)(3)(bath)] complexes have triclinic structure (P-1), while [Yb(L)(3)(phen)] complex has orthorhombic structure (P2(1)2(1)2(1)). The crystallography parameters were determined. The photoluminescence of the complexes demonstrated only bands resulted from F-2(5/2) -> F-2(7/2) transition and corresponding three Stark subcomponents generated due to the crystal field action. NIR-OLED structures with emitting layers based on the [Yb(L)(3)(bipy)], [Yb(L)(3)(bath)], and [Yb(L)(3)(phen)] complexes have been fabricated, and their electroluminescence demonstrated maxima intensities at 978 and 1005 nm. Comparison of NIR-OLEDs power density showed that the maximal power densities of 2.17 (978 nm) and 1.92 (1005 nm) mu W x cm(-2) were determined for the NIR-OLED based on [Yb(L)(3)(bath)] complex.