High pressure synthesis and the valence state of vanadium ions for the novel transition metal pernitride, CuAl2-type VN2

被引：5

作者：

Asano, Shuto ^{[1
]}

Niwa, Ken ^{[1
]}

Sasaki, Takuya ^{[1
]}

Gaida, Nico Alexander ^{[1
]}

Hasegawa, Masashi ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Mat Phys, Nagoya, Aichi 4648603, Japan

来源：

DALTON TRANSACTIONS | 2022年 / 51卷 / 07期

关键词：

CRYSTAL-STRUCTURES; PLATINUM; NITRIDES;

D O I：

10.1039/d1dt04310b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel transition metal pernitride, CuAl2-type VN2, has been synthesized at a pressure above 73.3 GPa. The bulk modulus has been determined to be K-0 = 347(12) GPa. By hard X-ray absorption spectrum measurements of VN2, the valence state of transition metal ions in pernitrides has been for the first time experimentally reported.

引用

页码：2656 / 2659

页数：4

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