Synthesis and spectroscopic properties of a series of metal-free and metallo-phthalocyanines substituted with 8-quinolinoxy moieties

被引：0

作者：

Li, Wei-Li ^{[1
]}

Ma, Ji-Cheng ^{[1
]}

Li, Wen-Ju ^{[1
]}

Fu, Qiang ^{[1
]}

Wang, Kun ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2011年 / 03期

关键词：

phthalocyanines; synthesis; 8-quinolinoxy; UV-Vis; fluorescence; NONLINEAR-OPTICAL PROPERTIES; MICROWAVE-ASSISTED SYNTHESIS; ELECTROCHEMISTRY; ZINC; METALLOPHTHALOCYANINES; FLUORESCENCE; COMPLEXES; COBALT;

D O I：

10.3184/174751911X12970818575209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Peripherally tetraquinolinoxy-substituted, metal-free phthalocyanines and metallo-phthalocyanines 1c-f, 2c-f have been synthesised by reaction of an inorganic salt with phthalonitriles substituted with 5-(phenylamino)methyl-8-quinolinoxy and 5-[(4-chlorophenylamino) methyl]-8-quinolinoxy groups, respectively. The effects of metal ions [Zn(II), Cu(II), Co(II); N, i(II)], substituent, solvent and concentration on the UV-Vis spectra of these new complexes and their fluorescent properties are also described. The diamagnetic Zn(II) and Ni(II) complexes display intense fluorescence.

引用

页码：135 / 139

页数：5

共 44 条

[1] Enhancement of solubility via esterification: Synthesis and characterization of octakis (ester)-substituted phthalocyanines
Akkurt, Barbaros
Hamuryudan, Esin
[J]. DYES AND PIGMENTS, 2008, 79 (02) : 153 - 158
[2] [Anonymous], 1993, PHTHALOCYANINES PROP
[3] Synthesis, structure, spectroscopic properties, and electrochemistry of (1,8,15,22-tetrasubstituted phthalocyaninato)lead complexes
Bian, YZ
Li, L
Dou, JM
Cheng, DYY
Li, RJ
Ma, CQ
Ng, DKP
Kobayashi, N
Jiang, JZ
[J]. INORGANIC CHEMISTRY, 2004, 43 (23) : 7539 - 7544
[4] The microwave-assisted synthesis and characterization of novel metal-free and metallophthalocyanines peripherally fused to four 13-membered diazadithia macrocycles
Celenk, Elif
Kantekin, Halit
[J]. DYES AND PIGMENTS, 2009, 80 (01) : 93 - 97
[5] 3RD-ORDER NONLINEAR-OPTICAL PROPERTIES OF SOLUBLE OCTASUBSTITUTED METALLOPHTHALOCYANINES
DIAZGARCIA, MA
LEDOUX, I
DURO, JA
TORRES, T
AGULLOLOPEZ, F
ZYSS, J
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (35) : 8761 - 8764
[6] Nonlinear optical properties of tetrapyrazinoporphyrazinato indium chloride complexes due to excited-state absorption processes
Dini, D
Hanack, M
Meneghetti, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (26) : 12691 - 12696
[7] Separation and mesogenic properties of tetraalkoxy-substituted phthalocyanine isomers
Durmus, M
Yesilot, S
Ahsen, V
[J]. NEW JOURNAL OF CHEMISTRY, 2006, 30 (05) : 675 - 678
[8] Structure and electrical conduction properties of phthalocyanine thin films
Gould, RD
[J]. COORDINATION CHEMISTRY REVIEWS, 1996, 156 : 237 - 274
[9] Nanoscale organization of a phthalocyanine-fullerene system:: Remarkable stabilization of charges in photoactive 1-D nanotubules
Guldi, DM
Gouloumis, A
Vázquez, P
Torres, T
Georgakilas, V
Prato, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (16) : 5811 - 5813
[10] Synthesis of phthalocyanines with tridentate branched bulky and alkylthio groups
Hamuryudan, E
Merey, S
Bayir, ZA
[J]. DYES AND PIGMENTS, 2003, 59 (03) : 263 - 268

← 1 2 3 4 5 →