Thermal stability assessment of a new energetic Ca(II) compound with ZTO ligand by DSC and ARC

被引:8
作者
Zhu, Jiaping [1 ,2 ]
Fu, Shuqin [1 ,2 ]
Li, Keyao [1 ]
Zeng, Xierong [1 ]
Chen, Shaojun [1 ]
机构
[1] Shenzhen Univ, Guangdong Res Ctr Interfacial Engn Funct Mat, Nanshan Dist Key Lab Biopolymers & Safety Evaluat, Shenzhen Key Lab Polymer Sci & Technol,Coll Mat S, Shenzhen 518060, Peoples R China
[2] Shenzhen Univ, Coll Optoelect Engn, Key Lab Optoelect Devices & Syst, Minist Educ & Guangdong Prov, Shenzhen 518060, Peoples R China
基金
中国国家自然科学基金;
关键词
Ca(H2O)(6)center dot(HZTO center dot 2H(2)O)(2); Crystal structure; DSC; ARC; Thermal behavior; METAL-ORGANIC FRAMEWORKS; KINETIC PARAMETERS; HAZARD ASSESSMENT; THERMOSTABILITY; DECOMPOSITION; PERFORMANCE; DETONATION; SALTS; MOF;
D O I
10.1007/s10973-018-7552-9
中图分类号
O414.1 [热力学];
学科分类号
摘要
A new energetic Ca(H2O)(6)(HZTO2H(2)O)(2) was crystallized in the monoclinic space group C2/c, and its thermal characteristics and kinetics were studied by differential scanning calorimetry (DSC) and accelerating rate calorimetry (ARC). DSC measurements showed one endothermic peak and one exothermic peak with decomposition occurring at 286.8, 290.5, 296.5, and 303.2 degrees C at different heating rates (2.5, 5, 10, and 20 degrees Cmin(-1)). The critical temperature of thermal explosion (T-b) and kinetics parameters were calculated; the results show that Ca(HZTO2H(2)O)(2)6H(2)O is stable below 273.1 degrees C. The thermal behavior of Ca(H2O)(6)(HZTO2H(2)O)(2) under adiabatic condition was studied by ARC: The onset temperature was 185.7 degrees C, and the thermal decomposition ended at 228.2 degrees C within the time span of 458.1min. In addition, thermokinetic parameters such as the activation energy E-a and pre-exponential factor A under adiabatic condition were also obtained.
引用
收藏
页码:1873 / 1882
页数:10
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