Photoassociation spectroscopy of collisional pairs of mercury atoms: Determination of parameters of molecular terms

被引：5

作者：

Zuev, VS ^{[1
]}

Eden, JG

Tran, HC

机构：

[1] Russian Acad Sci, PN Lebedev Phys Inst, Moscow 117924, Russia

[2] Univ Illinois, Everitt Lab, Urbana, IL 61801 USA

来源：

OPTICS AND SPECTROSCOPY | 2001年 / 90卷 / 04期

基金：

美国国家科学基金会; 俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/1.1366744

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The photoassociation spectrum of an equilibrium vapor of mercury atoms in the range of 34960-37250 cm(-1) is recorded with the help of a tunable laser in observations of laser-induced fluorescence. The Franck-Condon structure, i.e., periodic variations in absorption intensity against a continuous background, is observed. The structure makes it possible to determine spectroscopic parameters of the upper attractive potential and the lower repulsive potential including that with a van der Waals well. The absorption spectrum of collisional pairs of mercury atoms is calculated using the Numerov-Cooley procedure for integrating the Schrodinger equation. Potential curves of the upper and lower states Hg-2(D1(u)) and Hg-2(X0(g)(+)) are determined by comparing the calculated spectra with the experimental one. (C) 2001 MAIK "Nauka/Interperiodica".

引用

页码：516 / 525

页数：10

共 23 条

[21] LASER MOLECULAR-SPECTROSCOPY - DETERMINATION OF PARAMETERS OF A VIBRATION-ROTATION ASR(1,1) LINE OF UPSILON-2 BAND OF AMMONIA IN ATMOSPHERE OF FOREIGN GASES [J].

BULANIN, MO ;

BULYCHEV, VP ;

LADVISHCHENKO, YM ;

KHODOS, EB .

OPTIKA I SPEKTROSKOPIYA, 1978, 44 (03) :444-449

[22] New facile and convenient synthesis of bispolyazamacrocycles using Boc protection. Determination of geometric parameters of dinuclear copper(II) complexes using ESR spectroscopy and molecular mechanics calculations [J].

Brandes, S ;

Gros, C ;

Denat, F ;

Pullumbi, P ;

Guilard, R .

BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1996, 133 (01) :65-73

[23] Inter- and intra-molecular contributions of neighboring dipolar pairs to the precise determination of interatomic distances in a simple [13C, 15N]-peptide by 13C, 15N-REDOR NMR spectroscopy [J].

Naito, A. ;

Nishimura, K. ;

Tuzi, S. ;

Saito, H. .

1600, (249) :2-5

← 1 2 3 →