Thermal and Mechanical Evaluation of Epoxy Resin Composites by Synthesis of Amine-Based Coupling Agent-Nano Silica Complex

被引:14
作者
Nikje, Mir Mohammad Alavi [1 ,2 ,3 ]
Garmarudi, Amir Bagheri [1 ,2 ,3 ]
Tehrani, Zahra Mazaheri [1 ]
Haghshenas, Moslem [2 ,3 ]
Shakhesi, Saeed [4 ]
机构
[1] IK Int Univ, Fac Sci, Dept Chem, Qazvin, Iran
[2] Engn Res Inst, Dept Chem, Tehran, Iran
[3] Engn Res Inst, Polymer Labs, Tehran, Iran
[4] Engn Res Inst, Res Affairs Dept, Tehran, Iran
关键词
Epoxy; Mechanical; Nano-complex; Nanocomposite; Silica; Thermal; TRIBOLOGICAL PERFORMANCE; INORGANIC PARTICLES; NANOCOMPOSITES; IRRADIATION; POLYMER; NANOPARTICLES; IMPROVEMENT; IMPACT; WEAR;
D O I
10.1080/03602559.2010.551388
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A chemical route was developed for pre-treatment of silica nano particles, prior to introducing the filler into the epoxy matrix in order to improve the compatibility of these phases. Silica nanoparticles were reacted with n-(2-aminoethyl)-3-aminopropyltrimethoxysilane (AEAP) coupling agent. The nanophase organic-inorganic complex was introduced into an epoxy-based polymer system. Effect of complexation was investigated on dispersion quality of nanoparticles in polymer matrix, while the physical and thermal properties of synthesized composites were studied by thermal and mechanical analysis tests. Nanoparticulate fillers showed an increasing effect on the stress-strain and thermal resistance behavior of epoxy structure.
引用
收藏
页码:646 / 650
页数:5
相关论文
共 26 条
[1]  
Adebahr T., 2001, EUROPEAN COATINGS J, V4, P144
[2]   Preparation methodologies of polymer matrix nanocomposites [J].
Avella, M ;
Errico, ME ;
Martelli, S ;
Martuscelli, E .
APPLIED ORGANOMETALLIC CHEMISTRY, 2001, 15 (05) :435-439
[3]   Tailoring of thermomechanical properties of thermoplastic nanocomposites by surface modification of nanoscale silica particles [J].
Becker, C ;
Krug, H ;
Schmidt, H .
BETTER CERAMICS THROUGH CHEMISTRY VII: ORGANIC/INORGANIC HYBRID MATERIALS, 1996, 435 :237-242
[4]   Positional assembly of hybrid polyurethane nanocomposites via incorporation of inorganic building blocks into organic polymer [J].
Chen, S ;
Sui, JJ ;
Chen, L .
COLLOID AND POLYMER SCIENCE, 2004, 283 (01) :66-73
[5]  
Dennis HR, 2001, PLAST ENG, V57, P56
[6]   Impact modified epoxy/montmorillonite nanocomposites: synthesis and characterization [J].
Isik, I ;
Yilmazer, U ;
Bayram, G .
POLYMER, 2003, 44 (20) :6371-6377
[7]   Improvement of Tensile and Flexural Properties in Epoxy/Clay Nanocomposites Reinforced with Weave Glass Fiber Reel [J].
Kumar, M. Ashok ;
Reddy, K. Hemachandra ;
Reddy, Y. V. Mohana ;
Reddy, G. Ramachandra ;
Naidu, S. Venkata .
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS, 2010, 59 (11) :854-862
[8]  
Laine RM, 2001, ADV MATER, V13, P800, DOI 10.1002/1521-4095(200106)13:11<800::AID-ADMA800>3.0.CO
[9]  
2-G
[10]   Organoclay-modified high performance epoxy nanocomposites [J].
Liu, WP ;
Hoa, SV ;
Pugh, M .
COMPOSITES SCIENCE AND TECHNOLOGY, 2005, 65 (02) :307-316