A charge-transfer host system composed of a chiral 1,1′-bi-2-naphthol cluster and benzylviologen

被引：10

作者：

Imai, Yoshitane ^{[1
]}

Kamon, Kensaku ^{[1
]}

Kinuta, Takafumi ^{[1
]}

Tajima, Nobuo ^{[2
]}

Sato, Tomohiro ^{[3
]}

Kuroda, Reiko ^{[3
,4
]}

Matsubara, Yoshio ^{[1
]}

机构：

[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan

[2] NIMS, Computat Mat Sci Ctr, First Principles Simulat Grp, Tsukuba, Ibaraki 3050047, Japan

[3] ERATO, JST, SORST Kuroda Chiromorphol Team, Meguro Ku, Tokyo 1530041, Japan

[4] Univ Tokyo, Grad Sch Arts & Sci, Dept Life Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

TETRAHEDRON | 2007年 / 63卷 / 48期

关键词：

1,1 '-bi-2-naphthol cluster; chiral CT complex; molecular recognition; solid-state host system; viologen;

D O I：

10.1016/j.tet.2007.09.018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral charge-transfer (CT) complexes composed of a chiral 1,1 '-bi-2-naphthol cluster as the electron donor and 1,1 '-dibenzyl-4,4 '- bipyridinium dichloride as the electron acceptor serve as a host system for molecular recognition. CT complexes that include guest alcohols show different diffuse reflectance spectra (DRS) depending on the included guest. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：11928 / 11932

页数：5

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