Coordination chemistry of scandium .1. Synthesis and crystal structure of scandium six-coordinate glycine complex [Sc-2(Gly)(6)(ClO4)(6)](n)

被引：7

作者：

Yan, CH

Zhang, YW

Li, BG

Jin, TZ

Xu, GG

机构：

[1] Stt. Key Lab. Rare Earth Mat., C., Peking University

来源：

POLYHEDRON | 1996年 / 15卷 / 17期

关键词：

D O I：

10.1016/0277-5387(95)00585-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex was synthesized in an aqueous solution of Sc(ClO4)(3), and its crystal structure was determined by an X-ray diffraction method. The complex has an infinite chain structure, built from dimeric units. Two scandium ions are combined by three simple bridging carboxyl groups from three glycine molecules. Only one type of bonding mode of the carboxyl groups is represented. Scandium exhibits an octahedral configuration. (C) 1996 Elsevier Science Ltd.

引用

页码：2895 / 2899

页数：5

共 18 条

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[2]

BRITTAIN HB, 1978, J AM CHEM SOC, V98, P8255

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